Doppler-free/Doppler-sliced ion imaging

Literature Information

Publication Date 2006-09-25
DOI 10.1039/B612324D
Impact Factor 3.676
Authors

Cunshun Huang, Sridhar A. Lahankar, Myung Hwa Kim, Bailin Zhang, Arthur G. Suits


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Abstract

We demonstrate a hybrid Doppler-free/Doppler-sliced ion imaging approach that is well-suited for detection of H or D atoms. The method relies on 2 + 1 resonant ionization with identical, nearly counterpropagating beams that are coplanar but directed at a small angle relative to the detector face. This results in Doppler selection of the velocity component along the time of flight axis but Doppler-free detection in the plane perpendicular to this axis. The results show high signal level and excellent slicing (∼5%), yielding velocity resolution completely determined by cation recoil in the ionization step.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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