Network-controlled unique reactivities of carbonyl groups in hollow and microporous organic polymer

Literature Information

Publication Date 2018-04-23
DOI 10.1039/C8CC02788A
Impact Factor 6.222
Authors

Myung Hyun Kim, Jaewon Choi, Kyoung Chul Ko, Kyoungil Cho, Ji Hoon Park, Sang Moon Lee, Hae Jin Kim, Yoon-Joo Ko, Jin Yong Lee, Seung Uk Son


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Abstract

Hollow and microporous organic network bearing alkynone moieties was prepared via carbonylative Sonogashira coupling. The carbonyl groups in the network showed unusual chemical reactivities, compared with those of a model alkynone compound. The observed differences between the reactivities of alkynones in the molecule and in the network were analyzed based on the “network effect”.

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