Palladium-catalyzed arene C–H activation/ketone C–H functionalization reaction: route to spirodihydroindenones
Literature Information
Publication Date
2017-04-12
DOI
10.1039/C7QO00164A
Impact Factor
5.281
Authors
Bo-Sheng Zhang, Hui-Liang Hua, Lu-Yao Gao, Ce Liu, Yi-Feng Qiu, Ping-Xin Zhou, Zhao-Zhao Zhou, Jia-Hui Zhao, Yong-Min Liang
View Original
Abstract
A novel palladium and norbornene catalyzed arene C–H activation method to synthesize various spirodihydroindenone derivatives was developed. This method produces spirodihydroindenones employing aryl iodides with 2-(2-bromoethyl)-cyclopentanones via a domino reaction, which simplifies the route of building spiro compounds and expands further applications for functional groups selectivity.
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Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
Recommended Compounds
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6-Bromo-2,3-dihydro-1H-pyrido[2,3-b][1,4]oxazine
CAS Number:
1203499-17-5
Molecular Formula:
C7H7BrN2O
N,N-Dimethyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2-pyrimidinamine
CAS Number:
1032759-30-0
Molecular Formula:
C12H20BN3O2
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