Twisted terrylene dyes: synthesis and application in organic solar cells

Literature Information

Publication Date 2017-03-16
DOI 10.1039/C7QO00118E
Impact Factor 5.281
Authors

Wei Jiang, Rui Xin, Bowei Xu, Jianqi Zhang, Zhixiang Wei, Jianhui Hou, Zhaohui Wang


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Abstract

Two twisted terrylene diimides (TDIs), namely TDI2 and BTDI3, have been designed and synthesized. In comparison to monomeric TDI, their molecular geometries and optoelectronic properties have been systematically investigated. BTDI3, with a highly twisted 3D geometry, shows the best light-absorbing capability in the range of 500–700 nm and a suitable LUMO level. Simultaneously, a preliminary exploration of their photovoltaic performances was carried out. The optimized device based on PBDT-TS1/BTDI3 produces a power conversion efficiency (PCE) of 3.64%, demonstrating the potential of terrylene dyes in the photovoltaics field.

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Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

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