Formation of a palladium(ii) complex of 2-(2-pyridinylmethyleneamino)-2′-hydroxy-1,1′-binaphthyl with novel Cσ-coordination and its theoretical investigation

Literature Information

Publication Date 2003-06-06
DOI 10.1039/B303477A
Impact Factor 6.222
Authors

Lijin Xu, Qian Shi, Xingshu Li, Xian Jia, Xin Huang, Ruihu Wang, Zhongyuan Zhou, Zhenyang Lin, Albert S. C. Chan


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Abstract

Complexation of the NOBIN-derived Schiff base ligand 1 with Pd(CH3CN)2Cl2 has been observed to result in a novel Pd–C bonding mode and theoretical calculations based on B3LYP density functional theory have been carried out to clarify the reaction mechanism.

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