The use of a germene for the synthesis of esters of α-germyl-substituted α-amino acid and α-aminophosphonic acid

Literature Information

Publication Date 2003-06-05
DOI 10.1039/B303661H
Impact Factor 6.222
Authors

J. Escudié, C. Couret, H. Ranaivonjatovo, M. Soufiaoui, H. Gornitzka


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Abstract

The first α-germyl-substituted α-amino ester and α-germyl-substituted α-aminophosphonic ester have been synthesized by a one-pot reaction between the germene Mes2GeCR2 (CR2 = fluorenylidene) and the iminoester or iminophosphonate Ph(H)CNCH2–Y (Y = COOMe, P(O)(OEt)2).

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