A heterobimetallic K2Ti2 complex incorporating two calix[5]arenes: A diverse array of metal–ligand interplay

Literature Information

Publication Date 2003-06-18
DOI 10.1039/B304449A
Impact Factor 6.222
Authors

Colin L. Raston


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Abstract

Reaction of p-tBu-calix[5]arene with potassium metal in a mixture of methanol and THF followed by [Ti(acac)2(OPri)2] affords an unsymmetrical dimeric 1∶1 K/Ti complex built up from a central Ti–O–Ti core with each titanium(IV) centre octahedrally coordinated, bearing an acac and a calix[5]arene encapsulating a potassium ion.

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