Ethylene/vinyl acetate-based macrocycles via organometallic-mediated radical polymerization and CuAAC ‘click’ reaction
Literature Information
Publication Date
2017-12-11
DOI
10.1039/C7PY01891F
Impact Factor
5.582
Authors
Jérémy Demarteau, Julien De Winter, Christophe Detrembleur, Antoine Debuigne
View Original
Abstract
Recent advances in organometallic-mediated radical polymerization led to unique α,ω-difunctional poly(vinyl acetate) (PVAc) and ethylene/vinyl acetate copolymers (EVA). A copper-catalyzed Huisgen dipolar cycloaddition ring-closure reaction was applied to these difunctional precursors paving the way to unprecedented PVAc and/or EVA macrocycles, and to their PVOH- and EVOH-counterparts after hydrolysis.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
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[2-(Benzyloxy)-3-bromo-5-methylphenyl]boronic acid
CAS Number:
870777-20-1
Molecular Formula:
C14H14BBrO3
![Imidazo[1,5-a]pyrazine structure](https://static.chemtradehub.com/structs/274/274-49-7-d749.webp "Imidazo[1,5-a]pyrazine structure")
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