Design of well-defined shape memory networks with high homogeneity: towards advanced shape memory polymeric materials
Literature Information
Publication Date
2017-06-15
DOI
10.1039/C7PY00904F
Impact Factor
5.582
Authors
Yi Pan, Zhaohui Zheng, Xiaobin Ding
View Original
Abstract
Designing precisely defined network architecture that could integrate desired material properties into a single network is a great challenge for the development of advanced polymeric materials. For thermally induced shape memory polymers, rapid response, controllable recovery in a narrow temperature window and a large achievable number of cycles are critical for their applications. Here, we report the synthesis of a well-defined shape memory network with high homogeneity via efficient step-growth thiol-norbornene photopolymerization. Because of the uniform distribution of the switch segments and netpoints, the single polymer network exhibits a combination of perfect shape fixity and recovery, rapid response, outstanding cycle life at the high strain and unusual tunable multiple shape memory effects in a narrow temperature range, which may lead to an even more diverse range of applications.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
![[(1S,2S,3R,4S,7R,9S,10S,12R,15S)-4,12-Diacetyloxy-15-[(2R,3S)-3-benzamido-3-phenyl-2-(2,2,2-trichloroethoxycarbonyloxy)propanoyl]oxy-1,9-dihydroxy-10,14,17,17-tetramethyl-11-oxo-6-oxatetracyclo[11.3.1.03,10.04,7]heptadec-13-en-2-yl] benzoate structure](https://static.chemtradehub.com/structs/100/100431-55-8-7104.webp "[(1S,2S,3R,4S,7R,9S,10S,12R,15S)-4,12-Diacetyloxy-15-[(2R,3S)-3-benzamido-3-phenyl-2-(2,2,2-trichloroethoxycarbonyloxy)propanoyl]oxy-1,9-dihydroxy-10,14,17,17-tetramethyl-11-oxo-6-oxatetracyclo[11.3.1.03,10.04,7]heptadec-13-en-2-yl] benzoate structure")
2,2-dideuterio-2-(3,4,5,6-tetradeuterio-2-pyridyl)acetic acid;hydrochloride
CAS Number:
1329799-67-8
Molecular Formula:
C7H2ClD6NO2
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