(1H-Benzotriazol-1-yloxy)(di-1-pyrrolidinyl)methylium hexafluorophosphate
CAS Number:
105379-24-6
Molecular Formula:
C15H21F6N5OP
Advantages and limitations of diisocyanates in intramolecular collapse
Literature Information
Publication Date
2017-05-26
DOI
10.1039/C7PY00712D
Impact Factor
5.582
Authors
Feng Wang, Charles E. Diesendruck
View Original
Abstract
A comprehensive examination of the synthesis of single chain polymer nanoparticles (SCPNs) from a copolymer of methyl acrylate (MA) and 2-hydroxyethyl acrylate (HEA) via the intra-chain urethane formation by using hexamethylene diisocyanate (HDI) as a cross-linker is described. By introducing model urethane, urea, and amine compounds, the resulting SCPNs were carefully characterized by NMR, DSC, IR and GPC. In addition to the advantages of using cheap and accessible commercially available materials, the effects of the long reaction time under high dilution or harsher heating conditions on the cross-linking chemistry are studied, providing clear limitations on the use of this chemistry for intra-chain collapse.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
(3beta,7beta,12beta)-3,7,12-Trihydroxy-11,15,23-trioxolanost-8-en-26-oic acid
CAS Number:
98665-22-6
Molecular Formula:
C30H44O8
![[4-(Heptyloxy)phenyl]boronic acid structure](https://static.chemtradehub.com/structs/136/136370-19-9-ad33.webp "[4-(Heptyloxy)phenyl]boronic acid structure")
![N-[(Benzyloxy)carbonyl]serine structure](https://static.chemtradehub.com/structs/276/2768-56-1-77f7.webp "N-[(Benzyloxy)carbonyl]serine structure")
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