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Fe-Porphyrin functionalized microporous organic nanotube networks and their application for the catalytic olefination of aldehydes and carbene insertion into N–H bonds
Literature Information
Publication Date
2017-05-31
DOI
10.1039/C7PY00530J
Impact Factor
5.582
Authors
Minghong Zhou, Hui Zhang, Linfeng Xiong, Zidong He, Tianqi Wang, Yang Xu, Kun Huang
View Original
Abstract
Novel meso-tetraphenylporphyrin iron(III) chloride (Fe(TPP)Cl) functionalized microporous organic nanotube networks (Fe(TPP)Cl-MONNs) were successfully synthesized by an in situ hyper-crosslinking reaction between core–shell bottlebrush copolymers and Fe(TPP)Cl. The obtained Fe(TPP)Cl-MONN catalyst possesses a hierarchical porous structure, large surface area and good stability, which exhibits high catalytic activity and excellent reusability in the olefination of aldehydes and carbene insertion into N–H bonds with ethyl diazoacetate.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
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