Oxidative polymerization of catecholamines: structural access by high-resolution mass spectrometry

Literature Information

Publication Date 2017-04-26
DOI 10.1039/C7PY00506G
Impact Factor 5.582
Authors

Christiane Lang, Kathryn E. Fairfull-Smith


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Abstract

We introduce the high-resolution electrospray ionization mass spectrometric (ESI MS) structural elucidation of polymerized 3,4-dihydroxy-L-phenylalanine (L-DOPA) carrying 1-methoxy-2,2,6,6-tetramethylpiperidin-4-amide groups in the side chain. Critically, our powerful ESI MS platform unambiguously revealed the structurally diverse character of this multifunctional bio-adhesive polymer system.

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Polymer Chemistry

Polymer Chemistry
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