Metal-free electrophilic phosphination of electron-rich arenes, arenols and aromatic thiols with diarylphosphine oxides

Literature Information

Publication Date 2017-11-27
DOI 10.1039/C7OB02620J
Impact Factor 3.876
Authors

Tao Yuan, Shenlin Huang, Chun Cai, Guo-ping Lu


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Abstract

A new protocol for achieving the phosphination of arenes, arenols and thiols has been disclosed. This chemistry, in which diaryl(((trifluoromethyl)sulfonyl)oxy)phosphines as a kind of electrophilic phosphination reagents are in situ generated from diarylphosphine oxides, provides an efficient and mild approach for the synthesis of aromatic organophosphorus compounds.

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Organic & Biomolecular Chemistry

Organic & Biomolecular Chemistry
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