Convenient synthesis of versatile syndiotactic polystyrene materials containing pendant alkenyl groups with a scandium catalyst system
Literature Information
Publication Date
2018-06-11
DOI
10.1039/C8PY00607E
Impact Factor
5.582
Authors
Ke Yang, Hui Niu, Zhenghai Shi, Rui Tan, Tingting Li, Kaihua Shen, Yang Li
View Original
Abstract
The syndioselective copolymerization of styrene (St) with five alkenyl functionalized styrenic monomers with the use of [(C5Me4SiMe3)Sc(CH2C6H4NMe2-o)2]/[Ph3C][B(C6F5)4] produced a new family of versatile syndiotactic polystyrene (sPS) materials with pendant alkenyl groups (CC: 5–20 mol%, Tm: 220–250 °C). These styrenic monomers were divinylbenzene (FSt1), 4-isopropenylstyrene (FSt2), 4-(1-isopropylvinyl)styrene (FSt3), 4-(2-propenyl)styrene (FSt4) and 4-(2-methyl-2-propenyl)styrene (FSt5). Through thiol–ene click chemistry and epoxidation, new polar-group functionalized sPS materials were obtained efficiently, demonstrating that syndiotactic copolymers with pendant alkenyl groups can serve as reactive intermediates to produce various functional materials.
Recommended Journals
Construction and Building Materials
Diamond and Related Materials
Bio-Medical Materials and Engineering
Computational Materials Science
Journal of Physical Organic Chemistry
Catalysis Today
Applied Composite Materials
Main Group Metal Chemistry
Advanced Powder Technology
Journal of Computer-Aided Molecular Design
Related Literature
Fluorescent covalent organic frameworks for environmental pollutant detection sensors and enrichment sorbents: a mini-review
Qiuyi Liu, Yulian Yang, Yuemeng Zou, Luchun Wang, Zhu Li, Mingyue Wang, Lingling Li, Meng Tian, Dandan Wang, Die Gao
2023-10-18
Minireview
DOI: 10.1039/D3AY01166F
Catechol-tetraethylenepentamine co-deposition modified cellulose filter paper for α-glucosidase immobilization and inhibitor screening from traditional Chinese medicine
Guang-Zhen Wan, Chun-Lin Zhang, Juan Chen
2023-10-30
Paper
DOI: 10.1039/D3AY01835K
Milk exosomes anchored with hydrophilic and zwitterionic motifs enhance mucus permeability for applications in oral gene delivery
Chenzhen Zhang, Hengli Zhang, Héctor A. Millán Cotto, Timothy L. Boyer, Matthew R. Warren, Chia-Ming Wang, Joshua Luchan, Pradeep K. Dhal, Rebecca L. Carrier, Ambika G. Bajpayee
2023-11-23
Paper
DOI: 10.1039/D3BM01089A
A novel copper-based nanozyme: fabrication and application for colorimetric detection of resveratrol
Wanxin Li, Jiaxin Sun, Yao Xin, Yu Han, Yanyang Sun, Aijun Li, Zhi Wang
2023-11-13
Paper
DOI: 10.1039/D3AY01666H
A comparison of size exclusion chromatography-based tandem strategies for plasma exosome enrichment and proteomic analysis
H. H. Bai, X. F. Wang, B. Y. Zhang, W. Liu
2023-11-02
Paper
DOI: 10.1039/D3AY01704D
Determination of total phenol and six polyphenolic components in the polyphenol extract of Cinnamomi cortex by quantitative nuclear magnetic resonance spectroscopy
Dan-Yang Shi, Yu Zheng, Qiang-Sheng Guo, Can Gong, Xu Xu, Jian-Ping Gao
2023-11-13
Paper
DOI: 10.1039/D3AY01501G
Nano-in-nano enteric protein delivery system: coaxial Eudragit® L100-55 fibers containing poly(N-vinylcaprolactam) nanogels
Ana Sonzogni, Guadalupe Rivero, Verónica Gonzalez, Gustavo Abraham, Roque Minari
2023-11-22
Paper
DOI: 10.1039/D3BM01422C
Advances in biomedical systems based on microneedles: design, fabrication, and application
Xinghao Wang, Zifeng Wang, Min Xiao, Zhanhong Li, Zhigang Zhu
2023-11-07
Review Article
DOI: 10.1039/D3BM01551C
Low-cost electronic-nose (LC-e-nose) systems for the evaluation of plantation and fruit crops: recent advances and future trends
Jose Lucena Barbosa, Jr, Mohammed Kamruzzaman, Douglas Fernandes Barbin
2023-10-18
Critical Review
DOI: 10.1039/D3AY01192E
You might also like
Compound Q&A
What are the main uses of 4-Nitrophenyl phosphate disodium salt hexahydrate (CAS: 333338-18-4)?
4-Nitrophenyl phosphate disodium salt hexahydrate is primarily used as a substra...
333338-18-44-Nitrophenyl phosph...
Compound Q&A
What are the main uses of 2-(Trifluoromethyl)-1,3-oxazole-4-carboxylic Acid (CAS: 1060816-01-4)?
2-(Trifluoromethyl)-1,3-oxazole-4-carboxylic Acid (CAS: 1060816-01-4) is widely ...
1060816-01-42-(Trifluoromethyl)-...
Compound Q&A
How should 2-Fluoro-4-biphenylcarboxylic acid (CAS: 137045-30-8) be stored?
2-Fluoro-4-biphenylcarboxylic acid should be stored in a cool, dry place at room...
137045-30-82-Fluoro-4-biphenylc...
Compound Q&A
What industries use Prednisolone-21-Carboxylic Acid (CAS: 61549-70-0)?
Prednisolone-21-Carboxylic Acid is primarily used in the pharmaceutical industry...
61549-70-0Prednisolone-21-Carb...
Compound Q&A
How should 4-(Hydrazinomethyl)-1,2,3-benzenetriol (CAS: 3614-72-0) be stored?
4-(Hydrazinomethyl)-1,2,3-benzenetriol (CAS: 3614-72-0) should be stored in a co...
3614-72-04-(Hydrazinomethyl)-...
Compound Q&A
What industries use 4-Amino-1-methyl-1H-pyrazole-5-carboxylic acid hydrochloride (CAS: 92534-70-8)?
4-Amino-1-methyl-1H-pyrazole-5-carboxylic acid hydrochloride (CAS: 92534-70-8) i...
92534-70-84-Amino-1-methyl-1H-...
Compound Q&A
What regulatory guidelines apply to dehydropachymic acid (CAS: 77012-31-8)?
Dehydropachymic acid (CAS: 77012-31-8) is regulated by various agencies. It fall...
77012-31-8Dehydropachymic acid
Compound Q&A
What is the market or research trend for 6-[(2,2-Dimethylpropanoyl)amino]nicotinic acid (CAS: 898561-66-5)?
The market and research trends for 6-[(2,2-Dimethylpropanoyl)amino]nicotinic aci...
898561-66-56-[(2,2-Dimethylprop...
Compound Q&A
How should 1,10-Phenanthroline-2,9-dicarbaldehyde (CAS: 57709-62-3) be stored?
1,10-Phenanthroline-2,9-dicarbaldehyde should be stored in a cool, dry place awa...
57709-62-31,10-Phenanthroline-...
Compound Q&A
How is 5-Carbamoyl-11-oxo-10,11-dihydro-5H-dibenzo[b,f]azepin-10-yl acetate (CAS: 113952-21-9) typically synthesized?
5-Carbamoyl-11-oxo-10,11-dihydro-5H-dibenzo[b,f]azepin-10-yl acetate can be synt...
113952-21-95-Carbamoyl-11-oxo-1...
Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
![S-[2,3-Bis(palmitoyloxy)propyl]-N-[(9H-fluoren-9-ylmethoxy)(hydroxy)methylene]cysteine structure](https://static.chemtradehub.com/structs/210/210532-98-2-f6a7.webp "S-[2,3-Bis(palmitoyloxy)propyl]-N-[(9H-fluoren-9-ylmethoxy)(hydroxy)methylene]cysteine structure")
S-[2,3-Bis(palmitoyloxy)propyl]-N-[(9H-fluoren-9-ylmethoxy)(hydroxy)methylene]cysteine
CAS Number:
210532-98-2
Molecular Formula:
C53H83NO8S
![[(1S,2S,3R,4S,7R,9S,10S,12R,15S)-4,12-Diacetyloxy-15-[(2R,3S)-3-benzamido-3-phenyl-2-(2,2,2-trichloroethoxycarbonyloxy)propanoyl]oxy-1,9-dihydroxy-10,14,17,17-tetramethyl-11-oxo-6-oxatetracyclo[11.3.1.03,10.04,7]heptadec-13-en-2-yl] benzoate structure](https://static.chemtradehub.com/structs/100/100431-55-8-7104.webp "[(1S,2S,3R,4S,7R,9S,10S,12R,15S)-4,12-Diacetyloxy-15-[(2R,3S)-3-benzamido-3-phenyl-2-(2,2,2-trichloroethoxycarbonyloxy)propanoyl]oxy-1,9-dihydroxy-10,14,17,17-tetramethyl-11-oxo-6-oxatetracyclo[11.3.1.03,10.04,7]heptadec-13-en-2-yl] benzoate structure")
Recommended Suppliers
Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.