Convenient synthesis of versatile syndiotactic polystyrene materials containing pendant alkenyl groups with a scandium catalyst system
Literature Information
Publication Date
2018-06-11
DOI
10.1039/C8PY00607E
Impact Factor
5.582
Authors
Ke Yang, Hui Niu, Zhenghai Shi, Rui Tan, Tingting Li, Kaihua Shen, Yang Li
View Original
Abstract
The syndioselective copolymerization of styrene (St) with five alkenyl functionalized styrenic monomers with the use of [(C5Me4SiMe3)Sc(CH2C6H4NMe2-o)2]/[Ph3C][B(C6F5)4] produced a new family of versatile syndiotactic polystyrene (sPS) materials with pendant alkenyl groups (CC: 5–20 mol%, Tm: 220–250 °C). These styrenic monomers were divinylbenzene (FSt1), 4-isopropenylstyrene (FSt2), 4-(1-isopropylvinyl)styrene (FSt3), 4-(2-propenyl)styrene (FSt4) and 4-(2-methyl-2-propenyl)styrene (FSt5). Through thiol–ene click chemistry and epoxidation, new polar-group functionalized sPS materials were obtained efficiently, demonstrating that syndiotactic copolymers with pendant alkenyl groups can serve as reactive intermediates to produce various functional materials.
Recommended Journals
Related Literature
Engineering the outcome of cofermentation processes by altering the feedstock sugar-to-protein ratio
R. Bevilacqua, M. Mauricio-Iglesias, S. Balboa, J. M. Lema, M. Carballa
2022-05-26
Paper
DOI: 10.1039/D2EW00144F
Tunable cyano substituents in D–A conjugated polymers accessed via direct arylation for photocatalytic hydrogen production
Yu-Jie Zhang, Zhi-Rong Tan, Yu-Qin Xing, Zhengwang Chen, Jia-Bin Qiu, Shi-Yong Liu
2022-10-18
Communication
DOI: 10.1039/D2CC04625C
Metal directed assembly of ditopic containers and their complexes with alkylammonium salts
Edoardo Menozzi, Julius Rebek Jr.
2005-10-11
Communication
DOI: 10.1039/B509189F
Alkylation of 2-bromophosphinines using lithium trialkylborohydrides
Paper
DOI: 10.1039/CC9960000971
Conversion of glucose and cellulose into value-added products in water and ionic liquids
Jinliang Song, Honglei Fan, Jun Ma, Buxing Han
2013-07-31
Tutorial Review
DOI: 10.1039/C3GC41141A
Amphiphilic stilbene derivatives attenuate the neurotoxicity of soluble Aβ42 oligomers by controlling their interactions with cell membranes
Zhengxin Yu, Weijie Guo, Shrey Patel, Hong-Jun Cho, Liang Sun
2022-10-19
Edge Article
DOI: 10.1039/D2SC02654F
Variation from closed-shell to open shell electronic structures in oligothiophene bis(dioxolene) complexes
Paul D. Miller, David A. Shultz, Joshua Mengell, Lukasz Wojtas
2023-10-09
Edge Article
DOI: 10.1039/D3SC02341A
Co-doped MoS2 nanosheet: a stable and pH-universal electrocatalyst for an efficient hydrogen evolution reaction
Xiaojie Tan, Depeng Zhao, Yuchen Sun, Zhongxin Duan, Xiaowei Wang
2022-08-24
Paper
DOI: 10.1039/D2CE00951J
You might also like
Compound Q&A
What are the main uses of 4-Nitrophenyl phosphate disodium salt hexahydrate (CAS: 333338-18-4)?
4-Nitrophenyl phosphate disodium salt hexahydrate is primarily used as a substra...
333338-18-44-Nitrophenyl phosph...
Compound Q&A
What are the main uses of 2-(Trifluoromethyl)-1,3-oxazole-4-carboxylic Acid (CAS: 1060816-01-4)?
2-(Trifluoromethyl)-1,3-oxazole-4-carboxylic Acid (CAS: 1060816-01-4) is widely ...
1060816-01-42-(Trifluoromethyl)-...
Compound Q&A
How should 2-Fluoro-4-biphenylcarboxylic acid (CAS: 137045-30-8) be stored?
2-Fluoro-4-biphenylcarboxylic acid should be stored in a cool, dry place at room...
137045-30-82-Fluoro-4-biphenylc...
Compound Q&A
What industries use Prednisolone-21-Carboxylic Acid (CAS: 61549-70-0)?
Prednisolone-21-Carboxylic Acid is primarily used in the pharmaceutical industry...
61549-70-0Prednisolone-21-Carb...
Compound Q&A
How should 4-(Hydrazinomethyl)-1,2,3-benzenetriol (CAS: 3614-72-0) be stored?
4-(Hydrazinomethyl)-1,2,3-benzenetriol (CAS: 3614-72-0) should be stored in a co...
3614-72-04-(Hydrazinomethyl)-...
Compound Q&A
What industries use 4-Amino-1-methyl-1H-pyrazole-5-carboxylic acid hydrochloride (CAS: 92534-70-8)?
4-Amino-1-methyl-1H-pyrazole-5-carboxylic acid hydrochloride (CAS: 92534-70-8) i...
92534-70-84-Amino-1-methyl-1H-...
Compound Q&A
What regulatory guidelines apply to dehydropachymic acid (CAS: 77012-31-8)?
Dehydropachymic acid (CAS: 77012-31-8) is regulated by various agencies. It fall...
77012-31-8Dehydropachymic acid
Compound Q&A
What is the market or research trend for 6-[(2,2-Dimethylpropanoyl)amino]nicotinic acid (CAS: 898561-66-5)?
The market and research trends for 6-[(2,2-Dimethylpropanoyl)amino]nicotinic aci...
898561-66-56-[(2,2-Dimethylprop...
Compound Q&A
How should 1,10-Phenanthroline-2,9-dicarbaldehyde (CAS: 57709-62-3) be stored?
1,10-Phenanthroline-2,9-dicarbaldehyde should be stored in a cool, dry place awa...
57709-62-31,10-Phenanthroline-...
Compound Q&A
How is 5-Carbamoyl-11-oxo-10,11-dihydro-5H-dibenzo[b,f]azepin-10-yl acetate (CAS: 113952-21-9) typically synthesized?
5-Carbamoyl-11-oxo-10,11-dihydro-5H-dibenzo[b,f]azepin-10-yl acetate can be synt...
113952-21-95-Carbamoyl-11-oxo-1...
Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
6-Bromo-3,4-dihydro-2H-1,4-benzoxazine hydrochloride (1:1)
CAS Number:
1260803-10-8
Molecular Formula:
C8H9BrClNO
Recommended Suppliers
Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.