Long-range magnetic order in the porous metal–organic framework Ni(pyrazine)[Pt(CN)4]

Literature Information

Publication Date 2017-10-16
DOI 10.1039/C7CP06310E
Impact Factor 3.676
Authors

J. Alberto Rodríguez-Velamazán, Olivier Roubeau, Roberta Poloni, Elsa Lhotel, Elías Palacios, Miguel A. González, José A. Real


View Original

Abstract

A combined study involving DFT calculations, neutron scattering, heat capacity and magnetic measurements at very low temperatures demonstrates the long-range magnetic ordering of Ni(pyrazine)[Pt(CN)4] below 1.9 K, describing its antiferromagnetic spin arrangement. This compound belongs to the family of porous coordination polymers M(pyrazine)[Pt(CN)4] (M = divalent metal), renowned for showing interesting combinations of porosity and magnetic properties. The possibility of including long-range magnetic ordering, one of the most pursued functional properties, opens new perspectives for the multifunctionality of this class of compounds.

Related Literature

Non-percolating small metallic clusters and sharp suppression of metallicity in RE0.55Sr0.45Mn1−xRuxO3 manganites

H. S. Alagoz, I. Živković, K. H. Chow, J. Jung

2018-01-02 Paper

DOI: 10.1039/C7CP02423A

Panchromatic cross-conjugated π-bridge NIR dyes for DSCs

Yanbing Zhang, Hammad Cheema, Alexander E. London, Amber Morales, Jason D. Azoulay, Jared H. Delcamp

2018-01-08 Paper

DOI: 10.1039/C7CP06703H

Dynamic tailoring of electromagnetic behaviors of graphene plasmonic oligomers by local chemical potential

Junbo Ren, Wangqing Wang, Weibin Qiu, Pingping Qiu, Zeyu Wang, Zhili Lin, Jia-Xian Wang

2018-05-22 Paper

DOI: 10.1039/C8CP01281D

Interplay of proton and electron transfer to determine concerted behavior in the proton-coupled electron transfer of glutathione oxidation

Kejie Meng, Jonnathan Medina-Ramos, Emnet Yibeltal-Ashenafi, Julio C. Alvarez

2018-06-13 Paper

DOI: 10.1039/C8CP01415A

Analysis of competitive binding of several metal cations by graphene oxide reveals the quantity and spatial distribution of carboxyl groups on its surface

Rustem R. Amirov, Julia Shayimova, Zarina Nasirova, Alexander Solodov, Ayrat M. Dimiev

2017-12-12 Paper

DOI: 10.1039/C7CP07055A

Improvement of the photovoltaic parameters of perovskite solar cells using a reduced-graphene-oxide-modified titania layer and soluble copper phthalocyanine as a hole transporter

Esmaiel Nouri, Mohammad Reza Mohammadi, Zong-Xiang Xu, Vassilios Dracopoulos, Panagiotis Lianos

2017-12-20 Paper

DOI: 10.1039/C7CP04538G

You might also like

Compound Q&A

What industries use (1R,3S)-1,3-Cyclopentanediol (CAS: 16326-97-9)?

(1R,3S)-1,3-Cyclopentanediol finds applications in various industries. In the ph...

16326-97-9(1R,3S)-1,3-Cyclopen...
Compound Q&A

What precautions should be taken when handling N'-[4-(Dimethylamino)phenyl]-N,N-dimethyl-1,4-benzenediamine (CAS: 637-31-0)?

When handling N'-[4-(Dimethylamino)phenyl]-N,N-dimethyl-1,4-benzenediamine, it i...

637-31-0N'-[4-(Dimethylamino...
Compound Q&A

Are there alternatives to 5-(2,4-Difluorophenyl)-2-methoxypyrimidine (CAS: 1352318-16-1) in synthesis?

There are several alternatives to 5-(2,4-Difluorophenyl)-2-methoxypyrimidine in ...

1352318-16-15-(2,4-Difluoropheny...
Compound Q&A

What regulatory guidelines apply to 1-(3-Methoxyphenoxy)propan-2-ol (CAS: 382141-68-6)?

1-(3-Methoxyphenoxy)propan-2-ol (CAS: 382141-68-6) must comply with the Globally...

382141-68-61-(3-Methoxyphenoxy)...
Compound Q&A

Is Tetrodotoxin Citrate (CAS: 18660-81-6) safe?

Tetrodotoxin Citrate is extremely dangerous and should be handled with extreme c...

18660-81-6Tetrodotoxin Citrate
Compound Q&A

What are the main uses of 2-Methyl-2-propanyl [(1R,3S)-3-hydroxycyclopentyl]carbamate (CAS: 225641-84-9)?

2-Methyl-2-propanyl [(1R,3S)-3-hydroxycyclopentyl]carbamate (CAS: 225641-84-9) i...

225641-84-92-Methyl-2-propanyl ...
Compound Q&A

How should waste containing 4-(2-Hydroxyhexafluoroisopropyl)Benzoic Acid (CAS: 16261-80-6) be handled?

Waste containing 4-(2-Hydroxyhexafluoroisopropyl)Benzoic Acid (CAS: 16261-80-6) ...

16261-80-64-(2-Hydroxyhexafluo...
Compound Q&A

How is 2-Methyl-2-proanyl {(2S)-1-[(benzyloxy)amino]-3-hydroxy-3-methyl-1-oxo-2-butanyl}carbamate (CAS: 102507-19-7) typically synthesized?

2-Methyl-2-proanyl {(2S)-1-[(benzyloxy)amino]-3-hydroxy-3-methyl-1-oxo-2-butanyl...

102507-19-72-Methyl-2-propanyl ...
Compound Q&A

What is Benzeneethanamine, α-ethyl-, hydrochloride (1:1) (CAS: 20735-15-3)?

Benzeneethanamine, α-ethyl-, hydrochloride (1:1) is an organic compound with the...

20735-15-3Benzeneethanamine, α...
Compound Q&A

Are there alternatives to 3-{(E)-[4-(Dimethylamino)phenyl]diazenyl}benzoic acid (CAS: 20691-84-3) in synthesis?

In the synthesis of compounds similar to 3-{(E)-[4-(Dimethylamino)phenyl]diazeny...

20691-84-33-{(E)-[4-(Dimethyla...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.