Effect of fluorine substitution and position on phenylene spacer in carbazole based organic sensitizers for dye sensitized solar cells

Literature Information

Publication Date 2017-10-05
DOI 10.1039/C7CP05226J
Impact Factor 3.676
Authors

Mohammad Adil Afroz, Keval K. Sonigara, Telugu Bhim Raju, Saurabh S. Soni


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Abstract

The preparation of a series of organic dyes having a carbazole donor, cyanoacrylic acid as an acceptor, and phenylene ring as a spacer with the difference in the positions of fluorine substitution is reported. Due to its unique properties of small size and high electronegativity, fluorine is now being extensively used to control the optoelectronic properties of organic conjugated materials. In this study, the results revealed that the specific position and number of fluorine substitution were very crucial to control the optical as well as the electrochemical properties of organic dyes. It was found that fluorine substitution led to a redshift in the absorption spectra of the dyes and reduced the band gap. The injection rate of photoexcited electrons was measured using time-resolved photoluminescence and the o-fluoro substituted dye MA1F-o showed the best electron injection dynamics. As a result of broad absorption and high electron injection rate, the dye MA1F-o outperformed other dyes with a power conversion efficiency of 4.02% (Jsc = 8.3 mA cm−2, Voc = 0.75 V and FF = 0.64). The non-fluorinated dye MA0F exhibited a power conversion efficiency of 3.23% (Jsc = 6.8, Voc = 0.72 and FF = 0.67). The dye MA1F-m exhibited the least molar absorption coefficient and a lower power conversion efficiency because of the meta inductive effect.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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