Non-linear sweep voltammetry of adsorbed species: theory and a method to determine formal potentials
Literature Information
Enno Kätelhön, Richard G. Compton
Recent literature revealed the hitherto unexploited opportunities offered by unconventional cyclic voltammetry with non-triangular potential sweeps. We here investigate the implications of such techniques for the equilibrium voltammetry of surface-bound analytes and expose rather counter-intuitive effects: if only slightly different potential waveforms are applied, distinct and characteristic features arise in the voltammogram that can be readily exploited for quantitative analysis. Our work comprises a theoretical analysis and suggests initially a simple method to determine formal potentials.
Recommended Journals
Related Literature
Synergistic carrier and phonon transport advance Ag dynamically-doped n-type PbTe thermoelectrics via Mn alloying
Wei Yuan, Qian Deng, Dong Pan, Xiang An, Canyang Zhao, Wenjun Su, Zhengmin He
DOI: 10.1039/D3TA06594D
Green and sustainable bifunctional carbonized wood electrodes decorated with controlled nickel/α(β)-nickel(ii) hydroxide to boost overall water splitting
Jun Yong Yang, Jae Gyu Ahn, Boemjin Ko, Taeyoung Park, Soon-Jik Hong, Dongju Lee, Cheng Ai Li, Sung Ho Song
DOI: 10.1039/D3TA05519A
Skin-inspired gradient ionogels induced by electric field for ultrasensitive and ultrafast-responsive multifunctional ionotronics
Min Xu, Xuchao Shen, Shuaijie Li, Hongnan Zhu, Yan Cheng, Hongying Lv, Zhuoer Wang, Cunguang Lou, Hongzan Song
DOI: 10.1039/D3TA05723B
Lignin beyond the status quo: recent and emerging composite applications
Mahyar Fazeli, Hossein Baniasadi, Roozbeh Abidnejad, Muhammad Mujtaba, Juha Lipponen, Jukka Seppälä
DOI: 10.1039/D3GC03154C
Hexagonal 2D covalent organic frameworks from nonpolar and symmetric electron-accepting substituents for electron transport layers in near-infrared PeLEDs
Lili Xu, Lei Zheng, Yu Jing, Xiangyu Guo, Xuemin Hu, Bo Xu, Shengli Zhang
DOI: 10.1039/D3TA05200A
How to make membrane distillation greener: a review of environmentally friendly and sustainable aspects
Emilia Gontarek-Castro, Roberto Castro-Muñoz
DOI: 10.1039/D3GC03377E
Exploring finite-temperature electronic transport in CoSi alloys with transition metals (Cr, Mn, Fe, and Ni) using the KKR-CPA method
Ho Ngoc Nam, Katsuhiro Suzuki
DOI: 10.1039/D3TA06259G
Inorganic/organic composite fluorinated interphase layers for stabilizing ether-based electrolyte in high-voltage lithium metal batteries
Qimeng Ren, Qinglei Wang, Li Su, Guodong Liu, Yan Song, Xuehui Shangguan, Faqiang Li
DOI: 10.1039/D3TA05506J
Understanding the anion disorder governing lithium distribution and diffusion in an argyrodite Li6PS5Cl solid electrolyte
Taegon Jeon, Gyeong Ho Cha, Sung Chul Jung
DOI: 10.1039/D3TA06069A
Temperature and pressure induced structural transitions of lead iodide perovskites
Pratap Vishnoi, C. N. R. Rao
DOI: 10.1039/D3TA05315F
You might also like
How should waste containing 2-Ethyl-4-Methyl-1H-Imidazole-5-Carbaldehyde (CAS: 88634-80-4) be handled?
Waste containing 2-Ethyl-4-Methyl-1H-Imidazole-5-Carbaldehyde (CAS: 88634-80-4) ...
What industries use Triethoxy(octyl)silane (CAS: 1385031-14-0)?
Triethoxy(octyl)silane (CAS: 1385031-14-0) is widely used in the pharmaceuticals...
Are there alternatives to 3-iodo-7-nitro-1H-indazole (CAS: 864724-64-1) in synthesis?
Several alternatives to 3-iodo-7-nitro-1H-indazole (CAS: 864724-64-1) exist in t...
Are there alternatives to Benzene, bis[(trimethoxysilyl)ethyl] (CAS: 266317-71-9) in synthesis?
Yes, there are alternatives to Benzene, bis[(trimethoxysilyl)ethyl] (CAS: 266317...
Is Isothiazole-3-carbonitrile (CAS: 1452-17-1) safe?
Isothiazole-3-carbonitrile (CAS: 1452-17-1) is generally considered safe when us...
Is (3-Chlorophenyl)methanol (CAS: 873-63-2) safe?
(3-Chlorophenyl)methanol (CAS: 873-63-2) is considered low to moderately toxic. ...
How is (2S,3S)-2-Hydroxy-3-({[(2-methyl-2-propanyl)oxy]carbonyl}amino)-3-(2-naphthyl)propanoic acid (CAS: 959583-98-3) typically synthesized?
(2S,3S)-2-Hydroxy-3-({[(2-methyl-2-propanyl)oxy]carbonyl}amino)-3-(2-naphthyl)pr...
What precautions should be taken when handling Methyl 2-(bromomethyl)-5-methoxybenzoate (CAS: 788081-99-2)?
Proper handling of methyl 2-(bromomethyl)-5-methoxybenzoate requires the use of ...
What is 6,8-Dibromoimidazo[1,2-a]pyridine-2-carboxylic acid (CAS: 904805-36-3)?
6,8-Dibromoimidazo[1,2-a]pyridine-2-carboxylic acid (CAS: 904805-36-3) is an aro...
Is 3-Amino-5-bromo-2-pyridinecarbonitrile (CAS: 573675-27-1) safe?
3-Amino-5-bromo-2-pyridinecarbonitrile is considered safe when handled under pro...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.











![[3-Chloro-5-(diethylcarbamoyl)phenyl]boronic acid structure [3-Chloro-5-(diethylcarbamoyl)phenyl]boronic acid structure](https://static.chemtradehub.com/structs/957/957120-59-1-febc.webp)
![4-Nitrophenyl N-{[(2-methyl-2-propanyl)oxy]carbonyl}-L-isoleucinate structure 4-Nitrophenyl N-{[(2-methyl-2-propanyl)oxy]carbonyl}-L-isoleucinate structure](https://static.chemtradehub.com/structs/169/16948-38-2-c88f.webp)
