Low energy electron-induced decomposition of (η3-C3H5)Ru(CO)3Br, a potential focused electron beam induced deposition precursor with a heteroleptic ligand set

Literature Information

Publication Date 2017-05-02
DOI 10.1039/C7CP01696D
Impact Factor 3.676
Authors

Rachel M. Thorman, Joseph A. Brannaka, Lisa McElwee-White, Oddur Ingólfsson


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Abstract

Here we describe in detail low energy electron induced fragmentation of a potential focused electron beam induced deposition (FEBID) precursor, π-allyl ruthenium tricarbonyl bromide, i.e. (η3-C3H5)Ru(CO)3Br, specially designed to allow comparison of the effect of different ligands on the efficiency of low energy electron induced fragmentation of FEBID precursors. Specifically, we discuss the efficiency of dissociative electron attachment (DEA) and dissociative ionization (DI) with respect to electron-induced removal of the allyl, bromide and carbonyl ligands. We place this in perspective with a previous surface study on the same precursor and we propose a design strategy for FEBID precursor molecules to increase their susceptibility towards DEA.

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Contents list

2023-12-06 Front/Back Matter

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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