Comment on “Non-linear photoelectron effect contributes to the formation of negative matrix ions in UV-MALDI”

Literature Information

Publication Date 2017-06-05
DOI 10.1039/C7CP00454K
Impact Factor 3.676
Authors


View Original

Abstract

Alonso and Zenobi (AZ) recently claimed “a comprehensive theoretical description of negative ion formation in UV-MALDI” (Phys. Chem. Chem. Phys., 2016, 18, 19574). Emphasizing photoelectrons, it is found to be unphysical in several respects, including violation of charge and mass conservation, and in the treatment of ablation, expansion and electron capture. It is not internally consistent, and ions created by the photoelectron mechanism are given artificial preference. Although AZ claimed the “first proposal for a comprehensive theoretical description of negative ion formation in UV-MALDI”, the Coupled Physical and Chemical Dynamics model has successfully reproduced a number of phenomena relevant to negative ion production over many years.

Related Literature

Insight into the mechanism of the arylation of arenes via norbornene relay palladation through meta- to para-selectivity

Shengnan Liu, Qiong Wang, Fang Huang, Wenjuan Wang, Chong Yang, Jianbiao Liu, Dezhan Chen

2021-11-09 Research Article

DOI: 10.1039/D1QO01500A

Recent advances in catalytic enantioselective direct C–H bond functionalization of electron-deficient N-containing heteroarenes

Xiao-Lan Liu, Luo-Bin Jiang, Mu-Peng Luo, Zhi Ren, Shou-Guo Wang

2021-09-22 Review Article

DOI: 10.1039/D1QO01223A

Rhodium(iii)-catalyzed annulation of 3-arylquinazolinones with alkynes via double C–H activation: an efficient route for quinolino[2,1-b]quinazolinones

Jian Huang, Wei Chen, Jiazhi Liang, Qin Yang, Zhihong Deng, Zhibin Song, Yiyuan Peng

2021-09-27 Research Article

DOI: 10.1039/D1QO01186C

Photoredox-catalyzed synthesis of sulfonated oxazolines from N-allylamides through the insertion of sulfur dioxide

Zhichao Chen, Hong Zhang, Shu-Feng Zhou, Xiuling Cui

2021-11-30 Research Article

DOI: 10.1039/D1QO01540K

Figure-eight arylene ethynylene macrocycles: facile synthesis and specific binding behavior toward Hg2+

Hui Nie, Qian-Hui Li, Siqi Zhang, Chuan-Ming Wang, Wen-Hui Lin, Ke Deng, Li-Jin Shu, Qing-Dao Zeng, Jun-Hua Wan

2021-09-29 Research Article

DOI: 10.1039/D1QO00812A

Aziridine based electrophilic handle for aspartic acid ligation

Kiran Bajaj, Devesh S. Agarwal, Rajeev Sakhuja, Girinath G. Pillai

2018-05-16 Paper

DOI: 10.1039/C8OB00676H

From imines to amides via NHC-mediated oxidation

Shaofa Sun, Donghui Guo, Fangyi Li

2021-11-30 Research Article

DOI: 10.1039/D1QO01661J

O-Phenylenediamine: a privileged pharmacophore of ferrostatins for radical-trapping reactivity in blocking ferroptosis

Xie-Huang Sheng, Cheng-Cheng Cui, Chao Shan, Yu-Zhen Li, Duo-Hong Sheng, Bin Sun, De-Zhan Chen

2018-05-03 Paper

DOI: 10.1039/C8OB00546J

Hydroxyl group-directed, tartaric acid-catalyzed synthesis of meta-functionalized aryl ethers and phenols through domino conjugate addition/aromatization of para-quinols

Guo-Shu Chen, Jia-Hui Li, Shu-Jie Chen, Wen-Xia Lin, Hai Ren, Dong-Sheng Deng, Yun-Lin Liu

2021-10-02 Research Article

DOI: 10.1039/D1QO01078F

Efficient enantioselective synthesis of CF2H-containing dispiro[benzo[b]thiophene-oxindole-pyrrolidine]s via organocatalytic cycloaddition

Yabo Deng, Yongzhen Li, Yalan Wang, Shuo Sun, Sichao Ma, Pengfei Jia, Wenguang Li, Kairong Wang, Wenjin Yan

2021-11-24 Research Article

DOI: 10.1039/D1QO01392K

You might also like

Compound Q&A

What industries use (1R,3S)-1,3-Cyclopentanediol (CAS: 16326-97-9)?

(1R,3S)-1,3-Cyclopentanediol finds applications in various industries. In the ph...

16326-97-9(1R,3S)-1,3-Cyclopen...
Compound Q&A

What precautions should be taken when handling N'-[4-(Dimethylamino)phenyl]-N,N-dimethyl-1,4-benzenediamine (CAS: 637-31-0)?

When handling N'-[4-(Dimethylamino)phenyl]-N,N-dimethyl-1,4-benzenediamine, it i...

637-31-0N'-[4-(Dimethylamino...
Compound Q&A

Are there alternatives to 5-(2,4-Difluorophenyl)-2-methoxypyrimidine (CAS: 1352318-16-1) in synthesis?

There are several alternatives to 5-(2,4-Difluorophenyl)-2-methoxypyrimidine in ...

1352318-16-15-(2,4-Difluoropheny...
Compound Q&A

What regulatory guidelines apply to 1-(3-Methoxyphenoxy)propan-2-ol (CAS: 382141-68-6)?

1-(3-Methoxyphenoxy)propan-2-ol (CAS: 382141-68-6) must comply with the Globally...

382141-68-61-(3-Methoxyphenoxy)...
Compound Q&A

Is Tetrodotoxin Citrate (CAS: 18660-81-6) safe?

Tetrodotoxin Citrate is extremely dangerous and should be handled with extreme c...

18660-81-6Tetrodotoxin Citrate
Compound Q&A

What are the main uses of 2-Methyl-2-propanyl [(1R,3S)-3-hydroxycyclopentyl]carbamate (CAS: 225641-84-9)?

2-Methyl-2-propanyl [(1R,3S)-3-hydroxycyclopentyl]carbamate (CAS: 225641-84-9) i...

225641-84-92-Methyl-2-propanyl ...
Compound Q&A

How should waste containing 4-(2-Hydroxyhexafluoroisopropyl)Benzoic Acid (CAS: 16261-80-6) be handled?

Waste containing 4-(2-Hydroxyhexafluoroisopropyl)Benzoic Acid (CAS: 16261-80-6) ...

16261-80-64-(2-Hydroxyhexafluo...
Compound Q&A

How is 2-Methyl-2-proanyl {(2S)-1-[(benzyloxy)amino]-3-hydroxy-3-methyl-1-oxo-2-butanyl}carbamate (CAS: 102507-19-7) typically synthesized?

2-Methyl-2-proanyl {(2S)-1-[(benzyloxy)amino]-3-hydroxy-3-methyl-1-oxo-2-butanyl...

102507-19-72-Methyl-2-propanyl ...
Compound Q&A

What is Benzeneethanamine, α-ethyl-, hydrochloride (1:1) (CAS: 20735-15-3)?

Benzeneethanamine, α-ethyl-, hydrochloride (1:1) is an organic compound with the...

20735-15-3Benzeneethanamine, α...
Compound Q&A

Are there alternatives to 3-{(E)-[4-(Dimethylamino)phenyl]diazenyl}benzoic acid (CAS: 20691-84-3) in synthesis?

In the synthesis of compounds similar to 3-{(E)-[4-(Dimethylamino)phenyl]diazeny...

20691-84-33-{(E)-[4-(Dimethyla...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.