Intriguing transport dynamics of ethylammonium nitrate–acetonitrile binary mixtures arising from nano-inhomogeneity

Literature Information

Publication Date 2017-09-18
DOI 10.1039/C7CP04592A
Impact Factor 3.676
Authors

Alessandro Mariani, Matteo Bonomo, Boning Wu, Barbara Centrella, Danilo Dini, Edward W. Castner, Jr., Lorenzo Gontrani


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Abstract

Binary mixtures of ethylammonium nitrate and acetonitrile show interesting properties that originate from the structural and dynamical nano-heterogeneity present in ionic liquids. These effects are most pronounced when the ionic liquid is the minority compound. In this study the transport properties of such mixtures are studied, including viscosity, self-diffusion and conductivity. The results strongly support the presence of structural inhomogeneity and show an interesting composition-dependent behaviour in the mixtures.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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