Low temperature surfactant-free synthesis of monodisperse β-NaGdF4 nanorods by a novel ion-exchange process and their luminescence properties

Literature Information

Publication Date 2017-03-13
DOI 10.1039/C7CE00097A
Impact Factor 3.545
Authors

Lingfei Zhao, Ying Tao, Hongpeng You


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Abstract

In this paper, a rationally designed low temperature and surfactant-free ion-exchange strategy to synthesize monodisperse hexagonal NaGdF4 nanorods from a layered gadolinium hydroxynitrate precursor is reported for the first time. This novel synthetic process takes advantage of the structural similarity between the precursor and the hexagonal NaGdF4 to avoid the formation of the kinetically favored cubic phase. The formation mechanisms were discussed in detail by tracking the phase and morphology evolution during the reaction process. In addition, the downconversion and upconversion properties were investigated under laser excitation, and the products exhibited intense characteristic luminescence.

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Source Journal

CrystEngComm

CrystEngComm
CiteScore: 5.5
Self-citation Rate: 7.7%
Articles per Year: 643

CrystEngComm is the forum for the design and understanding of crystalline materials. We welcome studies on the investigation of molecular behaviour within crystals, control of nucleation and crystal growth, engineering of crystal structures, and construction of crystalline materials with tuneable properties and functions. We publish hypothesis-driven research into… how crystal design affects thermodynamics, phase transitional behaviours, polymorphism, morphology control, solid state reactivity (crystal-crystal solution-crystal, and gas-crystal reactions), optoelectronics, ferroelectric materials, non-linear optics, molecular and bulk magnetism, conductivity and quantum computing, catalysis, absorption and desorption, and mechanical properties. Using Techniques and methods including… Single crystal and powder X-ray, electron, and neutron diffraction, solid-state spectroscopy, spectrometry, and microscopy, modelling and data mining, and empirical, semi-empirical and ab-initio theoretical evaluations. On crystalline and solid-state materials. We particularly welcome work on MOFs, coordination polymers, nanocrystals, host-guest and multi-component molecular materials. We also accept work on peptides and liquid crystals. All papers should involve the use or development of a design or optimisation strategy. Routine structural reports or crystal morphology descriptions, even when combined with an analysis of properties or potential applications, are generally considered to be outside the scope of the journal and are unlikely to be accepted.

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