![Imidazo[1,5-a]pyrazine structure](https://static.chemtradehub.com/structs/274/274-49-7-d749.webp "Imidazo[1,5-a]pyrazine structure")
Phenol-selective mass spectrometric analysis of jet fuel
Literature Information
Publication Date
2017-07-26
DOI
10.1039/C7AN00908A
Impact Factor
4.616
Authors
Haoxuan Zhu, Eric Janusson, Jingwei Luo, James Piers, Farhana Islam, G. Bryce McGarvey, Allen G. Oliver, Ori Granot, J. Scott McIndoe
View Original
Abstract
Bromobenzyl compounds react selectively with phenols via the Williamson ether synthesis. An imidazolium charge-tagged bromobenzyl compound can be used to reveal phenol impurities in jet fuel by analysis via electrospray ionization mass spectrometry. The complex matrix as revealed by Cold EI GC/MS analysis is reduced to a few simple sets of compounds in the charge-tagged ESI mass spectrum, primarily substituted phenols and thiols. Examination of jet fuels treated by different refinery methods reveals the efficacy of these approaches in removing these contaminants.
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Source Journal
Analyst
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Analyst publishes analytical and bioanalytical research that reports premier fundamental discoveries and inventions, and the applications of those discoveries, unconfined by traditional discipline barriers.
Recommended Compounds
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2-(Methylsulfonyl)-2,4,5,6-tetrahydropyrrolo[3,4-c]pyrazole
CAS Number:
1226781-80-1
Molecular Formula:
C6H9N3O2S
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4-[(1-Methyl-1H-pyrrol-2-yl)methylene]-1,3(2H,4H)-isoquinolinedione
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Molecular Formula:
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