![[3-(2,6-Dichlorophenyl)-5-isopropyl-1,2-oxazol-4-yl]methanol structure](https://static.chemtradehub.com/structs/278/278597-30-1-5c79.webp "[3-(2,6-Dichlorophenyl)-5-isopropyl-1,2-oxazol-4-yl]methanol structure")
[3-(2,6-Dichlorophenyl)-5-isopropyl-1,2-oxazol-4-yl]methanol
CAS Number:
278597-30-1
Molecular Formula:
C13H13Cl2NO2
Selective deprotonation of tetra[3,4]thienylene in the presence of n-BuLi
Literature Information
Publication Date
2017-02-06
DOI
10.1039/C6QO00754F
Impact Factor
5.281
Authors
Bingbing Li, Chunli Li, Zhiying Ma, Li Xu, Hua Wang
View Original
Abstract
The sequential lithiation mechanism for the selective deprotonation of tetra[3,4]thienylene (1) to form Li4-1 in the present of n-BuLi in THF is investigated. The specific contralateral and ipsilateral selectivities of the lithiation sites in the different steps are explored. A series of tetra-substituted 1 are obtained, viaLi4-1 with electrophiles, in good yields.
Related Literature
Lactone synthesis activity in a site-directed mutant of an extradiol catechol dioxygenase enzyme
Sharon Mendel, Andrew Arndt, Timothy D. H. Bugg
2004-12-14
Communication
DOI: 10.1039/B414292F
The first organically templated open-framework metal selenate with a three-dimensional architecture
A. A. Ayi
2004-03-16
Communication
DOI: 10.1039/B400120F
SN2 vs. E2 on quaternary centres: an application to the synthesis of enantiopure β2,2-amino acids
Alberto Avenoza, Jesús H. Busto, Francisco Corzana, Gonzalo Jiménez-Osés, Jesús M. Peregrina
2004-03-16
Communication
DOI: 10.1039/B400282B
Cationic fac-tris(pyrazole) complexes as anion receptors
Sonia Nieto, Julio Pérez, Víctor Riera, Daniel Miguel, Celedonio Alvarez
2004-12-08
Communication
DOI: 10.1039/B414407D
Synthesis of poly(glycolide) in supercritical carbon dioxide in the presence of a hydrocarbon stabiliser
Daniel Bratton, Malcolm Brown, Steven M. Howdle
2004-02-24
Communication
DOI: 10.1039/B313358C
Synthesis of a β-diiminate iridium tetrahydride for arene C–H bond activation
Wesley H. Bernskoetter, Emil Lobkovsky, Paul J. Chirik
2004-02-27
Communication
DOI: 10.1039/B315817A
Formation of a palladium(ii) complex of 2-(2-pyridinylmethyleneamino)-2′-hydroxy-1,1′-binaphthyl with novel Cσ-coordination and its theoretical investigation
Lijin Xu, Qian Shi, Xingshu Li, Xian Jia, Xin Huang, Ruihu Wang, Zhongyuan Zhou, Zhenyang Lin, Albert S. C. Chan
2003-06-06
Communication
DOI: 10.1039/B303477A
Stable π-dimer of a tetrathiafulvalene cation radical encapsulated in the cavity of cucurbit[8]uril
Albina Y. Ziganshina, Young Ho Ko, Woo Sung Jeon, Kimoon Kim
2004-02-23
Communication
DOI: 10.1039/B316651A
A heterobimetallic K2Ti2 complex incorporating two calix[5]arenes: A diverse array of metal–ligand interplay
Colin L. Raston
2003-06-18
Communication
DOI: 10.1039/B304449A
You might also like
Compound Q&A
What precautions should be taken when handling 4-Methyl-6-(trifluoromethyl)quinoline (CAS: 40716-16-3)?
When handling 4-Methyl-6-(trifluoromethyl)quinoline (CAS: 40716-16-3), safety go...
40716-16-34-Methyl-6-(trifluor...
Compound Q&A
What is 4-(3,5-Difluorophenyl)aniline (CAS: 405058-00-6)?
4-(3,5-Difluorophenyl)aniline is an aromatic organic compound with the CAS numbe...
405058-00-64-(3,5-Difluoropheny...
Compound Q&A
How is 5-{[4-(Trifluoromethyl)phenyl]sulfanyl}-1,2,3-thiadiazole-4-carboxylic acid (CAS: 338982-07-3) typically synthesized?
5-{[4-(Trifluoromethyl)phenyl]sulfanyl}-1,2,3-thiadiazole-4-carboxylic acid can ...
338982-07-35-{[4-(Trifluorometh...
Compound Q&A
What is the market or research trend for 4-Benzylaniline hydrochloride (CAS: 6317-57-3)?
The market for 4-Benzylaniline hydrochloride (CAS: 6317-57-3) is steadily growin...
6317-57-34-Benzylaniline hydr...
Compound Q&A
Is [3-(Diethylsulfamoyl)phenyl]boronic acid (CAS: 871329-58-7) safe?
[3-(Diethylsulfamoyl)phenyl]boronic acid is generally considered safe when handl...
871329-58-7[3-(Diethylsulfamoyl...
Compound Q&A
What are the main uses of 3-Bromo-2,5-dimethoxyaniline (CAS: 115929-62-9)?
3-Bromo-2,5-dimethoxyaniline is mainly used in the pharmaceutical and chemical i...
115929-62-93-Bromo-2,5-dimethox...
Compound Q&A
What regulatory guidelines apply to N-Methyl-1-(5-methyl-1H-indol-3-yl)methanamine (CAS: 915922-67-7)?
N-Methyl-1-(5-methyl-1H-indol-3-yl)methanamine (CAS: 915922-67-7) is subject to ...
915922-67-7N-Methyl-1-(5-methyl...
Compound Q&A
What industries use Carbamic acid, N-[(5S)-5,6-diamino-6-oxohexyl]-, 1,1-dimethylethyl ester (CAS: 24828-96-4)?
This compound is primarily used in the pharmaceutical industry for the synthesis...
24828-96-4Carbamic acid, N-[(5...
Compound Q&A
How should 2-Methyl-2-propanyl [(1S,3R)-3-aminocyclohexyl]carbamate (CAS: 1298101-47-9) be stored?
2-Methyl-2-propanyl [(1S,3R)-3-aminocyclohexyl]carbamate (CAS: 1298101-47-9) sho...
1298101-47-92-Methyl-2-propanyl ...
Compound Q&A
What industries use Ethyl 2-bromo-4,4,4-trifluorobutanoate (CAS: 367-33-9)?
Ethyl 2-bromo-4,4,4-trifluorobutanoate (CAS: 367-33-9) is utilized in the pharma...
367-33-9Ethyl 2-bromo-4,4,4-...
Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
Recommended Compounds
![Methyl 3-({2'-[(E)-(hydroxyhydrazono)methyl]-4-biphenylyl}methyl)-2-oxo-2,3-dihydro-1H-benzimidazole-4-carboxylate structure](https://static.chemtradehub.com/structs/149/1499167-72-4-034a.webp "Methyl 3-({2'-[(E)-(hydroxyhydrazono)methyl]-4-biphenylyl}methyl)-2-oxo-2,3-dihydro-1H-benzimidazole-4-carboxylate structure")
Methyl 3-({2'-[(E)-(hydroxyhydrazono)methyl]-4-biphenylyl}methyl)-2-oxo-2,3-dihydro-1H-benzimidazole-4-carboxylate
CAS Number:
1499167-72-4
Molecular Formula:
C23H20N4O4
Recommended Suppliers
Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.