Copper and silver benzoate and aryl complexes and their implications for oxidative decarboxylative coupling reactions

Literature Information

Publication Date 2017-01-04
DOI 10.1039/C6QO00678G
Impact Factor 5.281
Authors

Andreas Baur, Katelyn A. Bustin, Ellen Aguilera, Jeffrey L. Petersen, Jessica M. Hoover


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Abstract

The synthesis and reactivity of phenanthroline-ligated copper and silver benzoate and aryl complexes are reported. The commonly proposed copper(I) and silver(I) aryl species are shown to be unlikely intermediates in the oxidative decarboxylative coupling reaction. Instead, the copper(II) benzoate undergoes decarboxylative coupling suggesting an unexpected copper(II) based pathway.

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Organic Chemistry Frontiers

Organic Chemistry Frontiers
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Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

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