Aliphatic C–H azidation through a peroxydisulfate induced radical pathway
Literature Information
Publication Date
2016-08-18
DOI
10.1039/C6QO00237D
Impact Factor
5.281
Authors
Xin Li
View Original
Abstract
A persulfate induced radical process to transform aliphatic tertiary C–H bonds into organic azides under transition-metal-free conditions has been developed. This method exhibits good chemo- and regioselectivity. A wide range of functional groups, including esters, halogens, azides, and dipeptides, are all tolerated well through the radical pathway, thus expanding the potential application of this method.
Recommended Journals
Related Literature
TiO2nanowire electron transport pathways inside organic photovoltaics
Pinyi Yang, Diane K. Zhong, Mingjian Yuan, Andrew H. Rice, Daniel R. Gamelin, Christine K. Luscombe
2013-02-01
Paper
DOI: 10.1039/C3CP50325A
Excited state interactions between flurbiprofen and tryptophan in drug–protein complexes and in model dyads. Fluorescence studies from the femtosecond to the nanosecond time domains
Ignacio Vayá, Paula Bonancía, M. Consuelo Jiménez, Dimitra Markovitsi, Thomas Gustavsson, Miguel A. Miranda
2013-01-23
Paper
DOI: 10.1039/C3CP43847C
2nd TYC workshop on energy materials
F. Baletto, J. Blumberger, A. Shluger
2013-02-20
Editorial
DOI: 10.1039/C2CP90214A
Towards low-cost flexible substrates for nanoplasmonic sensing
Lakshminarayana Polavarapu
2012-12-11
Perspective
DOI: 10.1039/C2CP43642F
Stability, surface features, and atom leaching of palladium nanoparticles: toward prediction of catalytic functionality
Hadi Ramezani-Dakhel, Peter A. Mirau, Rajesh R. Naik, Marc R. Knecht, Hendrik Heinz
2013-03-04
Communication
DOI: 10.1039/C3CP00135K
Infrared spectrum of the disilane cation (Si2H6+) from Ar-tagging spectroscopy
Marco Savoca, Martin Andreas Robert George, Judith Langer, Otto Dopfer
2013-01-17
Paper
DOI: 10.1039/C2CP43773B
Structure of pH sensitive self-assembled amphiphilic di- and triblock copolyelectrolytes: micelles, aggregates and transient networks
Céline Charbonneau, Christophe Chassenieux, Olivier Colombani, Taco Nicolai
2013-01-11
Paper
DOI: 10.1039/C3CP43653E
Template-free synthesis of 3D Nb3O7F hierarchical nanostructures and enhanced photocatalytic activities
Zheng Wang, Jungang Hou, Chao Yang, Shuqiang Jiao, Kai Huang, Hongmin Zhu
2013-01-24
Paper
DOI: 10.1039/C2CP44326K
You might also like
Compound Q&A
How should waste containing (6-Bromo-2-naphthyl)oxy](dimethyl)(2-methyl-2-propanyl)silane be handled?
Waste containing (6-Bromo-2-naphthyl)oxy](dimethyl)(2-methyl-2-propanyl)silane (...
100751-65-3[(6-Bromo-2-naphthyl...
Compound Q&A
How is 7-Fluoro-4-isoquinolinecarboxylic acid (CAS: 1841081-40-0) typically synthesized?
7-Fluoro-4-isoquinolinecarboxylic acid can be synthesized via a multi-step proce...
1841081-40-07-Fluoro-4-isoquinol...
Compound Q&A
What are the physical and chemical properties of 2,3,5,6-Tetrabromothieno[3,2-b]thiophene (CAS: 124638-53-5)?
2,3,5,6-Tetrabromothieno[3,2-b]thiophene is a crystalline compound with a high m...
124638-53-52,3,5,6-Tetrabromoth...
Compound Q&A
Is 1-[4-(Benzylamino)-7,8-dihydro-5H-pyrano[4,3-d]pyrimidin-2-yl]-2-methyl-1H-indole-4-carboxamide (CAS: 1542705-92-9) safe?
1-[4-(Benzylamino)-7,8-dihydro-5H-pyrano[4,3-d]pyrimidin-2-yl]-2-methyl-1H-indol...
1542705-92-91-[4-(Benzylamino)-7...
Compound Q&A
What is the market or research trend for imidazo[5,1-d]-1,2,3,5-tetrazine-8-carboxylic acid, 3,4-dihydro-3-methyl-4-oxo- (CAS: 113942-30-6)?
The market for imidazo[5,1-d]-1,2,3,5-tetrazine-8-carboxylic acid, 3,4-dihydro-3...
113942-30-6Imidazo[5,1-d]-1,2,3...
Compound Q&A
What is 3-(Triisopropylsilyl)propiolaldehyde (CAS: 163271-80-5)?
3-(Triisopropylsilyl)propiolaldehyde is a synthetic organic compound with the CA...
163271-80-53-(Triisopropylsilyl...
Compound Q&A
What regulatory guidelines apply to 6-Nitro-2H-1,4-benzoxazin-3(4H)-one (CAS: 81721-87-1)?
6-Nitro-2H-1,4-benzoxazin-3(4H)-one (CAS: 81721-87-1) is subject to various regu...
81721-87-16-Nitro-2H-1,4-benzo...
Compound Q&A
How should waste containing (3-Fluorophenyl)(4-{[(2-methyl-2-propanyl)oxy]carbonyl}-1-piperazinyl)acetic acid (CAS: 885272-91-3) be handled?
Waste containing (3-Fluorophenyl)(4-{[(2-methyl-2-propanyl)oxy]carbonyl}-1-piper...
885272-91-3(3-Fluorophenyl)(4-{...
Compound Q&A
What are the physical and chemical properties of N,N'-4,4'-Biphenyldiyldiisonicotinamide (CAS: 55119-40-9)?
N,N'-4,4'-Biphenyldiyldiisonicotinamide is a white crystalline solid with a mole...
55119-40-9N,N'-4,4'-Biphenyldi...
Compound Q&A
What industries use 6-Bromo-8-fluoro-2-quinazolinol (CAS: 1036756-15-6)?
6-Bromo-8-fluoro-2-quinazolinol is primarily used in the pharmaceutical industry...
1036756-15-66-Bromo-8-fluoro-2-q...
Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
Recommended Compounds
![2-{[4-(2-Methoxyethyl)phenoxy]methyl}oxirane structure](https://static.chemtradehub.com/structs/567/56718-70-8-f037.webp "2-{[4-(2-Methoxyethyl)phenoxy]methyl}oxirane structure")
Oxalic acid compound with cyclohexylsulfamothioic O-acid (11)
CAS Number:
31895-22-4
Molecular Formula:
C7H13NO4S3
Recommended Suppliers
Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.