α-Regioselective [3 + 2] annulations with Morita–Baylis–Hillman carbonates of isatins and 2-nitro-1,3-enynes
Literature Information
Publication Date
2016-05-16
DOI
10.1039/C6QO00118A
Impact Factor
5.281
Authors
Guang-Yao Ran, Pan Wang, Wei Du
View Original
Abstract
An α-regioselective asymmetric [3 + 2] annulation reaction with Morita–Baylis–Hillman carbonates of isatins and (E)-2-nitro-1,3-enynes catalysed by cinchona-derived amines has been developed, providing spirooxindoles with contiguous chiral centres including adjacent quaternary ones in moderate to good yields with high enantioselectivity and excellent diastereoselectivity.
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Source Journal
Organic Chemistry Frontiers
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