CuBr2-promoted cyclization and bromination of arene–alkynes: C–Br bond formation via reductive elimination of Cu(iii) species
Literature Information
Publication Date
2016-05-13
DOI
10.1039/C6QO00117C
Impact Factor
5.281
Authors
Wangsheng Liu, Jinjin Chen, Ruiwen Jin, Dawen Xu, Yawei Li, Feifei Ba, Guangxin Gu
View Original
Abstract
A CuBr2-promoted cyclization and bromination of arene–alkyne substrates has been developed, affording 9-bromophenanthrene derivatives highly efficiently. This reaction provides a novel and efficient protocol for C–Br bond formation from an inorganic bromine source via the reductive elimination of the Cu(III) species.
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Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
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