Pd-catalyzed aminocarbonylation of alkynes with amines using Co2(CO)8 as a carbonyl source
Literature Information
Publication Date
2016-03-28
DOI
10.1039/C6QO00075D
Impact Factor
5.281
Authors
Yaxi Dong, Suyan Sun, Fan Yang, Yu Zhu, Weiguo Zhu, Huijie Qiao, Yangjie Wu
View Original
Abstract
A simple and mild protocol for the synthesis of 2-ynamides by palladium-catalyzed aminocarbonylation of alkynes was developed. The reaction proceeded at room temperature in air, utilizing Co2(CO)8 as a carbonyl source. This aminocarbonylation reaction features mild reaction conditions and good tolerance of substrates especially including aryl amines and primary amines.
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Source Journal
Organic Chemistry Frontiers
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7.8
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724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
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