Synthesis and chiral recognition ability of helical polyacetylenes bearing helicene pendants
Literature Information
Publication Date
2014-06-09
DOI
10.1039/C4PY00692E
Impact Factor
5.582
Authors
Hiroki Iida, Tomoko Yamaguchi, Koutarou Hayashi, Daisuke Kumano, Jeanne Crassous, Nicolas Vanthuyne, Christian Roussel, Eiji Yashima
View Original
Abstract
Novel polyacetylenes bearing an optically active or racemic [6]helicene unit as the pendant groups directly bonded to the main-chain (poly-1s) were prepared by the polymerisation of the corresponding acetylenes (1-rac, 1-P and 1-M) using a rhodium catalyst. The optically active polyacetylenes (poly-1-P and poly-1-M) formed a preferred-handed helical conformation biased by the optically active helicene pendants, resulting in the induced circular dichroism (ICD) in their π-conjugated polymer backbone regions. The optically active helical polymers, when employed as an enantioselective adsorbent, showed a high chiral recognition ability towards racemates, such as the monomeric [6]helicene and 1,1′-binaphthyl analogues, and enantioselectively adsorbed one of the enantiomers.
Recommended Journals
European Journal of Wood and Wood Products
Pharmacological Reviews
Journal of Physics and Chemistry of Solids
Nature
Proceedings of the National Academy of Sciences of the United States of America
Pure and Applied Chemistry
Journal of Medicinal Chemistry
Helvetica Chimica Acta
Organic Preparations and Procedures International
Science
Related Literature
Twist angle and electric gating controllable electronic structure of the two-dimensional stacked BP homo-structure
Linwei Yao, Jiangni Yun, Peng Kang, Hongyuan Zhao, Siyu Zhang, Liru Zeng, Zhisong Bi, Junfeng Yan, Wu Zhao, Zhiyong Zhang
2023-11-20
Paper
DOI: 10.1039/D3CP03591C
Performance optimization of a thermoelectric generator for automotive application using an improved whale optimization algorithm
2023-10-31
Paper
DOI: 10.1039/D3SE01202F
Three-dimensional flower-like NiO on Cu foam as a lithiophilic current collector for high-performance lithium metal batteries
Bin Zhang, Changyong Huang, Xiaoqian Shi, Yong Liu, Guangmin Zhou
2023-11-01
Communication
DOI: 10.1039/D3SE01262J
Exploring the structural stability and electrochemical performance of B doped T-graphene nanotubes from first-principles calculations
Ruyan Zhang, Yuhua Hou, Xialei Guo, Xinyu Li, Wei Li, Xiaoma Tao, Youlin Huang
2023-11-29
Paper
DOI: 10.1039/D3CP04143C
Computational screening of single-atom doped In2O3 catalysts for the reverse water gas shift reaction
2023-11-29
Paper
DOI: 10.1039/D3CP04352E
Expression of concern: Optimization of a compact layer of TiO2via atomic-layer deposition for high-performance perovskite solar cells
Ahmed Esmail Shalan, Sudhakar Narra, Tomoya Oshikiri, Kosei Ueno, Xu Shi, Hui-Ping Wu, Mahmoud M. Elshanawany, Eric Wei-Guang Diau
2023-11-16
Expression of Concern
DOI: 10.1039/D3SE90087H
Solvent-controlled synthesis of hydrophilic and hydrophobic carbon dots
Chenhan Zhang, Zhihua Ying, Yuan Jiang, Haiyang Wang, Xuebin Zhou, Weipeng Xuan, Peng Zheng
2023-12-08
Paper
DOI: 10.1039/D3CP04273A
Coronene: a model for ultrafast dynamics in graphene nanoflakes and PAHs
Alberto Martín Santa Daría, Lola González-Sánchez, Sandra Gómez
2023-09-26
Paper
DOI: 10.1039/D3CP03656A
Studies on bimetallic Cu–Ag supported alumina catalysts for hydrodeoxygenation of 5-hydroxymethylfurfural to 2,5-dimethylfuran‡
B. Srinivasa Rao
2023-11-07
Paper
DOI: 10.1039/D3SE01096A
Halogen bond catalysis of the [4+2] cycloaddition reaction of 2-alkenylindoles: catalytic modes and stereoselectivity
Ying Li, Chang Zhao, Huaiyu Zhang, Yanli Zeng
2023-12-04
Paper
DOI: 10.1039/D3CP05479A
You might also like
Compound Q&A
What is Ethyl 3-cyclohexylpropanoate (CAS: 10094-36-7)?
Ethyl 3-cyclohexylpropanoate is a clear, colorless to light yellow liquid with a...
10094-36-7Ethyl 3-cyclohexylpr...
Compound Q&A
How should waste containing 2-(Hydroxymethyl)-5-(methoxycarbonyl)-6-methyl-4-(2-nitrophenyl)nicotinic acid (CAS: 34783-31-8) be handled?
Waste containing 2-(Hydroxymethyl)-5-(methoxycarbonyl)-6-methyl-4-(2-nitrophenyl...
34783-31-82-(Hydroxymethyl)-5-...
Compound Q&A
How should waste containing 2,4,6-Tris(pentafluoroethyl)-1,3,5-triazine (CAS: 858-46-8) be handled?
Waste containing 2,4,6-Tris(pentafluoroethyl)-1,3,5-triazine (CAS: 858-46-8) sho...
858-46-82,4,6-Tris(pentafluo...
Compound Q&A
What precautions should be taken when handling Chloroac-nle-oh (CAS: 56787-36-1)?
When handling Chloroac-nle-oh (CAS: 56787-36-1), it is essential to wear appropr...
56787-36-1Chloroac-nle-oh
Compound Q&A
What industries use Ethyl 6-phenylimidazo[2,1-b][1,3]thiazole-3-carboxylate (CAS: 752244-05-6)?
Ethyl 6-phenylimidazo[2,1-b][1,3]thiazole-3-carboxylate is primarily used in the...
752244-05-6Ethyl 6-phenylimidaz...
Compound Q&A
Are there alternatives to alpha-(2-Bromophenyl)benzylamine (CAS: 55095-15-3) in synthesis?
Alternatives to alpha-(2-Bromophenyl)benzylamine (CAS: 55095-15-3) in synthesis ...
55095-15-3alpha-(2-Bromophenyl...
Compound Q&A
How should waste containing 2-Chloro-5-methoxypyridine (CAS: 139585-48-1) be handled?
Waste containing 2-Chloro-5-methoxypyridine (CAS: 139585-48-1) should be managed...
139585-48-12-Chloro-5-methoxypy...
Compound Q&A
What industries use 1-(4-Methoxyphenyl)-2,5-dimethyl-1H-pyrrole (CAS: 5044-27-9)?
1-(4-Methoxyphenyl)-2,5-dimethyl-1H-pyrrole (CAS: 5044-27-9) is used in various ...
5044-27-91-(4-Methoxyphenyl)-...
Compound Q&A
Are there alternatives to 3-Bromo-5-(N-Boc)aminomethylisoxazole (CAS: 903131-45-3) in synthesis?
There are alternative reagents and compounds that can be used in the synthesis o...
903131-45-33-Bromo-5-(N-Boc)ami...
Compound Q&A
What is Tungsten(IV) oxide (CAS: 12036-22-5)?
Tungsten(IV) oxide, also known as tungsten dioxide, is a chemical compound with ...
12036-22-5Tungsten(IV) oxide
Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
![2-{3-[4-(3-Chlorophenyl)-1-piperazinyl]propyl}[1,2,4]triazolo[4,3-a]pyridin-3(2H)-one hydrochloride (1:1) structure](https://static.chemtradehub.com/structs/253/25332-39-2-496e.webp "2-{3-[4-(3-Chlorophenyl)-1-piperazinyl]propyl}[1,2,4]triazolo[4,3-a]pyridin-3(2H)-one hydrochloride (1:1) structure")
2-{3-[4-(3-Chlorophenyl)-1-piperazinyl]propyl}[1,2,4]triazolo[4,3-a]pyridin-3(2H)-one hydrochloride (1:1)
CAS Number:
25332-39-2
Molecular Formula:
C19H23Cl2N5O
Recommended Suppliers
Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.