Visible light mediated aerobic radical C–H phosphorization toward arylphosphonates
Literature Information
Publication Date
2016-04-18
DOI
10.1039/C6QO00049E
Impact Factor
5.281
Authors
Pan Peng, Long Peng, Guangyu Wang, Fangyu Wang, Yi Luo, Aiwen Lei
View Original
Abstract
A visible light mediated radical C–H phosphorization of benzothiazoles with O2 as the sole oxidant was developed towards the synthesis of various 2-diarylphosphoryl benzothiazoles. The phosphonyl radical was identified by EPR experiments. In situ31P NMR experiments showed that Ph2P(O)H mainly converted into the desired product and the oxidative byproduct Ph2P(O)OH.
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Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
Recommended Compounds
(S)-(9H-Fluoren-9-yl)methyl (pyrrolidin-2-ylmethyl)carbamate hydrochloride
CAS Number:
1217813-15-4
Molecular Formula:
C20H23ClN2O2
1-(3-Fluorophenyl)-1H-1,2,4-triazole-3-carboxylic acid
CAS Number:
1292369-51-7
Molecular Formula:
C9H6FN3O2
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