Copper-catalyzed crosscoupling of vinyl nitrenes and CF3-carbenes to synthesize CF3-2-azadienes
Literature Information
Publication Date
2023-11-07
DOI
10.1039/D3QO01537H
Impact Factor
5.281
Authors
Yongjuan Jiao, Tao Wu, Xinyu Zhang
View Original
Abstract
A unique and efficient copper catalytic system has been established to synthesize fluorinated 2-azadienes from isoxazoles and CF3-N-tosylhydrazones via crosscoupling reactions of vinyl nitrenes with CF3-carbenes. A proposed reaction pathway involves the tandem cleavage of N–O/C–N bonds and formation of a C–N double bond. The developed method features a broad substrate scope, easy handling, step economy, and well-defined regio- and stereoselectivities.
Recommended Journals
Related Literature
Molecules for organic electronics studied one by one
Jörg Meyer, Anja Wadewitz, Lokamani, Cormac Toher, Roland Gresser, Karl Leo, Moritz Riede, Francesca Moresco
2011-07-28
Paper
DOI: 10.1039/C1CP20999J
Bias-stress effects in organic field-effect transistors based on self-assembled monolayer nanodielectrics
Florian Colléaux, James M. Ball, Paul H. Wöbkenberg, Peter J. Hotchkiss, Seth R. Marder, Thomas D. Anthopoulos
2011-06-20
Paper
DOI: 10.1039/C1CP20769E
Graphical prediction of quantum interference-induced transmission nodes in functionalized organic molecules
Troels Markussen, Robert Stadler, Kristian S. Thygesen
2011-06-28
Paper
DOI: 10.1039/C1CP20924H
Excitons in semiconducting carbon nanotubes: diameter-dependent photoluminescence spectra
Yoshihiko Kanemitsu
2011-07-07
Perspective
DOI: 10.1039/C1CP21235D
Broadening of the derivative discontinuity in density functional theory
P. Schmitteckert
2011-07-27
Paper
DOI: 10.1039/C1CP21247H
MnO2/TiN heterogeneous nanostructure design for electrochemical energy storage
Stefanie A. Sherrill, Jonathon Duay, Zhe Gui, Parag Banerjee, Gary W. Rubloff
2011-07-20
Paper
DOI: 10.1039/C1CP21815H
Extraction of the surface trap level from photoluminescence: a case study of ZnO nanostructures
Haiping He, Yanjie Wang, Jingrui Wang, Zhizhen Ye
2011-07-11
Communication
DOI: 10.1039/C1CP21527B
Double layer capacitance of anode/solid-electrolyte interfaces
2011-07-25
Paper
DOI: 10.1039/C1CP20508K
Spin seebeck coefficient of a molecular spin pump
Jonas Fransson, Michael Galperin
2011-06-07
Paper
DOI: 10.1039/C1CP20720B
The role of disorder on the electronic structure of conjugated polymers. The case of poly-2,5-bis(phenylethynyl)-1,3,4-thiadiazole
J.M. Granadino-Roldán, M. Fernández-Gómez, Lin-Wang Wang
2011-07-08
Paper
DOI: 10.1039/C1CP20329K
You might also like
Compound Q&A
How should 2-Methylbenzene-1,4-diamine dihydrochloride (CAS: 615-45-2) be stored?
2-Methylbenzene-1,4-diamine dihydrochloride (CAS: 615-45-2) should be stored in ...
615-45-22-Methylbenzene-1,4-...
Compound Q&A
Is (1S,4S)-2,5-Diazabicyclo[2.2.1]heptane dihydrobromide (CAS: 132747-20-7) safe?
(1S,4S)-2,5-Diazabicyclo[2.2.1]heptane dihydrobromide is generally considered sa...
132747-20-7(1S,4S)-2,5-Diazabic...
Compound Q&A
What industries use (6-Chloropyridazin-3-YL)methanamine (CAS: 871826-15-2)?
(6-Chloropyridazin-3-YL)methanamine finds applications in the pharmaceutical ind...
871826-15-2(6-Chloropyridazin-3...
Compound Q&A
What are the main uses of 2-Fluoro-3-methylphenol (CAS: 77772-72-6)?
2-Fluoro-3-methylphenol is primarily used in the synthesis of pharmaceuticals, p...
77772-72-62-Fluoro-3-methylphe...
Compound Q&A
What precautions should be taken when handling 3-Methoxy-4-nitrobenzonitrile (CAS: 177476-75-4)?
When handling 3-Methoxy-4-nitrobenzonitrile, it is important to wear appropriate...
177476-75-43-Methoxy-4-nitroben...
Compound Q&A
What precautions should be taken when handling 1,3-Oxazolo[4,5-b]pyridine-2(3H)-thione (CAS: 211949-57-4)?
When handling 1,3-Oxazolo[4,5-b]pyridine-2(3H)-thione (CAS: 211949-57-4), it is ...
211949-57-4[1,3]Oxazolo[4,5-b]p...
Compound Q&A
What regulatory guidelines apply to 4-Ethynylbenzamide (CAS: 90347-86-7)?
4-Ethynylbenzamide (CAS: 90347-86-7) falls under various regulatory guidelines i...
90347-86-74-Ethynylbenzamide
Compound Q&A
What are the main uses of 3-(2-Ethylphenyl)-2-thioxo-4-imidazolidinone (CAS: 186822-57-1)?
3-(2-Ethylphenyl)-2-thioxo-4-imidazolidinone is primarily used as an intermediat...
186822-57-13-(2-Ethylphenyl)-2-...
Compound Q&A
What is (2-Fluoro-6-methoxyphenyl)acetic acid (CAS: 500912-19-6)?
(2-Fluoro-6-methoxyphenyl)acetic acid, also known as 4-fluoro-3-methoxybenzoic a...
500912-19-6(2-Fluoro-6-methoxyp...
Compound Q&A
What is the market or research trend for 2-[4-(Hydroxymethyl)phenoxy]ethanol (CAS: 102196-18-9)?
Market trends for 2-[4-(Hydroxymethyl)phenoxy]ethanol (CAS: 102196-18-9) indicat...
102196-18-92-[4-(Hydroxymethyl)...
Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
Recommended Compounds
![[(5-Methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetic acid structure](https://static.chemtradehub.com/structs/509/50918-26-8-4ce8.webp "[(5-Methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetic acid structure")
[(5-Methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetic acid
CAS Number:
50918-26-8
Molecular Formula:
C5H6N2O2S2
![[5-fluoro-2-(morpholine-4-carbonyl)phenyl]boronic acid structure](https://static.chemtradehub.com/structs/121/1217501-26-2-505c.webp "[5-fluoro-2-(morpholine-4-carbonyl)phenyl]boronic acid structure")
[5-fluoro-2-(morpholine-4-carbonyl)phenyl]boronic acid
CAS Number:
1217501-26-2
Molecular Formula:
C11H13BFNO4
Recommended Suppliers
Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.