An organocatalytic enantioselective vinylogous Mannich reaction of α,α-dicyanoolefins with isatin N-Boc ketimines
Literature Information
Publication Date
2016-03-29
DOI
10.1039/C6QO00038J
Impact Factor
5.281
Authors
Yi Zhu, Yao Li, Qingbin Meng, Xin Li
View Original
Abstract
The first catalytic enantioselective vinylogous Mannich reaction of α,α-dicyanoolefins with ketimines derived from isatins has been developed. High yields and enantioselectivities were observed for the reaction of various ketimines and α,α-dicyanoolefins using a tertiary butyl substituted cinchona alkaloid type squaramide catalyst.
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Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
Recommended Compounds
![Bis[(1,2,3,4,5-eta)-1-(diphenylphosphino)cyclopentadienyl]iron structure](https://static.chemtradehub.com/structs/121/12150-46-8-ecd2.webp "Bis[(1,2,3,4,5-eta)-1-(diphenylphosphino)cyclopentadienyl]iron structure")
Bis[(1,2,3,4,5-eta)-1-(diphenylphosphino)cyclopentadienyl]iron
CAS Number:
12150-46-8
Molecular Formula:
C34H28FeP2
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