Allylic borylation of tertiary allylic alcohols: a divergent and straightforward access to allylic boronates

Literature Information

Publication Date 2016-03-01
DOI 10.1039/C6QO00009F
Impact Factor 5.281
Authors

Kohei Harada, Marina Nogami, Keiichi Hirano, Daisuke Kurauchi, Hisano Kato, Kazunori Miyamoto, Tatsuo Saito


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Abstract

A facile and divergent synthetic process for converting tertiary allylic alcohols to multiply substituted allylic boronates is reported. This methodology is especially effective for tertiary alcohol substrates, providing the corresponding allylic boronates in moderate to good yields.

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Organic Chemistry Frontiers

Organic Chemistry Frontiers
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Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

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