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Post-polymerization modification of reactive polymers derived from vinylcyclopropane: a poly(vinylcyclopropane) derivative with physical gelation and UCST behaviour in ethanol–water mixtures
Literature Information
Publication Date
2014-06-19
DOI
10.1039/C4PY00740A
Impact Factor
5.582
Authors
Denis H. Seuyep N., Daniel Szopinski, Gerrit A. Luinstra, Patrick Theato
View Original
Abstract
In this paper we describe a new polymer that combines an upper critical solution temperature (UCST) and reversible physical gelation in ethanol–water mixtures. The polymer, namely poly(1-cyano-N-propylcarboxyamidovinylcyclopropane) (poly(CNPCAVCP)), was synthesized by post-polymerization modification of poly(1-cyano-1-pentafluorophenoxycarbonyl-2-vinylcyclopropane) (poly(CPFPCVCP)) with n-propylamine. The stimuli responsiveness of the polymer was investigated in ethanol and ethanol–water mixtures by varying the water concentration in the mixture. It was found that, depending on the water concentration, the mixture features an upper critical solution temperature (UCST), physical gelation or both. In addition, it was observed that the hysteresis between the heating and the cooling phase was very large (about 45 °C).
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
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