Controlled TfOH- or AuCl-catalyzed cycloisomerization and tandem hydrolytic defluorination of 1,2-allenyl perfluoroalkyl ketones
Literature Information
Publication Date
2016-03-30
DOI
10.1039/C6QO00001K
Impact Factor
5.281
Authors
Can Xue, Xin Huang, Shangze Wu, Chunling Fu, Shengming Ma
View Original
Abstract
An efficient TfOH- or AuCl-catalyzed cycloisomerization reaction of easily available n-perfluoroalkyl 1,2-allenyl ketones occurring smoothly to form 2-perfluoroalkyl furans has been reported. In the presence of TfOH and H2O, a corresponding tandem hydrolytic defluorination afforded multi-substituted furan-2-yl n-perfluoroalkyl ketones.
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Organic Chemistry Frontiers
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