(−)-Riboflavin (vitamin B2) and flavin mononucleotide as visible light photo initiators in the thiol–ene polymerisation of PEG-based hydrogels
Literature Information
Publication Date
2016-12-20
DOI
10.1039/C6PY02034H
Impact Factor
5.582
Authors
G. Kwandou, P. T. Spicer
View Original
Abstract
The photoinitiators used in light mediated hydrogelation have been limited due to cytotoxicity and solubility issues. Here we report the use of riboflavin and flavin mononucleotide as nontoxic, naturally occurring photoinitiators for the thiol–ene hydrogelation of functionalised poly(ethylene glycol). High Resolution Magic Angle Spinning (HRMAS) NMR spectroscopy and oscillatory rheometry were used to probe the efficiency of these initiators for this hydrogel system. The gelation and reaction progression could easily be manipulated using different initiator concentrations and light intensities.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
Ethyl 2,4-bis(trifluoromethyl)-5-pyrimidinecarboxylate
CAS Number:
188781-15-9
Molecular Formula:
C9H6F6N2O2
![(R)-N-[(S)-1-[2-(Diphenylphosphino)phenyl]ethyl]-2-methylpropane-2-sulfinamide structure](https://static.chemtradehub.com/structs/159/1595319-98-4-33e7.webp "(R)-N-[(S)-1-[2-(Diphenylphosphino)phenyl]ethyl]-2-methylpropane-2-sulfinamide structure")
(R)-N-[(S)-1-[2-(Diphenylphosphino)phenyl]ethyl]-2-methylpropane-2-sulfinamide
CAS Number:
1595319-98-4
Molecular Formula:
C24H28NOPS
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