An alternative method to estimate the bulk backbiting rate coefficient in acrylate radical polymerization
Literature Information
Publication Date
2016-10-04
DOI
10.1039/C6PY01468B
Impact Factor
5.582
Authors
Yoshi W. Marien, Paul H. M. Van Steenberge, Marie-Françoise Reyniers, Guy B. Marin
View Original
Abstract
Based on a pulsed laser polymerization-size exclusion chromatography (PLP-SEC) analysis, an alternative method to estimate the bulk backbiting rate coefficient kbb in acrylate radical polymerization is presented. For different solvent volume fractions (0–0.75), using the unsaturated analogue of the monomer as a solvent to rule out solvent effects, regression analysis is applied to inflection point data in the low frequency range (
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Source Journal
Polymer Chemistry
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