![3-(benzotriazol-1-yl)-N-[[2-[(3-bromophenyl)methoxy]phenyl]methylideneamino]propanamide structure](https://static.chemtradehub.com/structs/559/5595-78-8-0a32.webp "3-(benzotriazol-1-yl)-N-[[2-[(3-bromophenyl)methoxy]phenyl]methylideneamino]propanamide structure")
3-(benzotriazol-1-yl)-N-[[2-[(3-bromophenyl)methoxy]phenyl]methylideneamino]propanamide
CAS Number:
5595-78-8
Molecular Formula:
C32H52O2
The active role of excited states of phenothiazines in photoinduced metal free atom transfer radical polymerization: singlet or triplet excited states?
Literature Information
Publication Date
2016-09-06
DOI
10.1039/C6PY01410K
Impact Factor
5.582
Authors
Steffen Jockusch, Yusuf Yagci
View Original
Abstract
The active role of phenothiazine excited states in photoinduced metal-free atom transfer radical polymerization (ATRP) was investigated by using laser flash photolysis, fluorescence, phosphorescence and electron spin resonance spectroscopy. Weak fluorescence emission and short lifetimes of the singlet excited state (2.01 ns) together with high intersystem crossing quantum yields (∼0.6) and long triplet lifetimes (40 μs) indicate efficient intersystem crossing into the triplet state and its dominant role in a degenerative electron transfer process in photoinduced metal free ATRP.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
![4-Chloro-N-{[4-(dimethylamino)phenyl]carbamoyl}benzenesulfonamide structure](https://static.chemtradehub.com/structs/558/5581-42-0-7dcb.webp "4-Chloro-N-{[4-(dimethylamino)phenyl]carbamoyl}benzenesulfonamide structure")
4-Chloro-N-{[4-(dimethylamino)phenyl]carbamoyl}benzenesulfonamide
CAS Number:
5581-42-0
Molecular Formula:
C15H16ClN3O3S
4-(Dibenzylamino)tetrahydro-2H-pyran-4-carbonitrile
CAS Number:
1630906-81-8
Molecular Formula:
C20H22N2O
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