Growth of well-ordered iron sulfide thin films
Literature Information
Earl Matthew Davis, Giulia Berti, Helmut Kuhlenbeck, Vedran Vonk, Hans-Joachim Freund
In this paper a growth recipe for well-ordered iron sulfide films and the results of their characterisation are presented. The film was studied using X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), low energy electron diffraction (LEED), and scanning tunneling microscopy (STM). XRD data reveal that the film has a NiAs-like structure with Fe vacancies, similar to iron sulfides such as pyrrhotite and smythite, although no indication of any ordering of these vacancies was observed. LEED and STM results show that the film exhibits a 2 × 2 surface reconstruction. XPS data provide additional evidence for a large number of Fe vacancies, and the oxidation states of the Fe and S in the film are analysed.
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.












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