Growth of well-ordered iron sulfide thin films

Literature Information

Publication Date 2019-08-28
DOI 10.1039/C9CP04157E
Impact Factor 3.676
Authors

Earl Matthew Davis, Giulia Berti, Helmut Kuhlenbeck, Vedran Vonk, Hans-Joachim Freund


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Abstract

In this paper a growth recipe for well-ordered iron sulfide films and the results of their characterisation are presented. The film was studied using X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), low energy electron diffraction (LEED), and scanning tunneling microscopy (STM). XRD data reveal that the film has a NiAs-like structure with Fe vacancies, similar to iron sulfides such as pyrrhotite and smythite, although no indication of any ordering of these vacancies was observed. LEED and STM results show that the film exhibits a 2 × 2 surface reconstruction. XPS data provide additional evidence for a large number of Fe vacancies, and the oxidation states of the Fe and S in the film are analysed.

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