![(3R,5R)-1-[(Benzyloxy)carbonyl]-5-methyl-3-piperidinecarboxylic acid structure](https://static.chemtradehub.com/structs/126/1269757-29-0-c552.webp "(3R,5R)-1-[(Benzyloxy)carbonyl]-5-methyl-3-piperidinecarboxylic acid structure")
(3R,5R)-1-[(Benzyloxy)carbonyl]-5-methyl-3-piperidinecarboxylic acid
CAS Number:
1269757-29-0
Molecular Formula:
C15H19NO4
Tailoring the structure of polymer networks with iniferter-mediated photo-growth
Literature Information
Publication Date
2016-04-01
DOI
10.1039/C6PY00325G
Impact Factor
5.582
Authors
Awaneesh Singh, Olga Kuksenok, Jeremiah A. Johnson, Anna C. Balazs
View Original
Abstract
Using dissipative particle dynamics (DPD), we developed a computational approach to capture the photo-controlled radical polymerization (“photo-growth”) of polymer gels containing trithiocarbonate (TTC) groups within the network strands. Using this model, we focused on a “primary gel” and illuminated the sample to activate the TTCs, which then interacted with monomer and cross-linker in the solution. At low TTC concentrations, gels composed of compatible monomers formed two distinct, spatially separated layers. Conversely, at high TTC concentration, gels formed from incompatible components displayed a well-intermixed structure. Hence, in the presence of light, variations in the TTC concentration provide a new approach for controllably tailoring the structure of polymer gels, and thereby tailoring the functionality of the network.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
cis-3-Amino-1-(trifluoromethyl)cyclobutanol hydrochloride (1:1)
CAS Number:
1408075-16-0
Molecular Formula:
C5H9ClF3NO
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