Isomerization of the methoxy radical revisited: the impact of water dimers

Literature Information

Publication Date 2016-09-22
DOI 10.1039/C6CP04544H
Impact Factor 3.676
Authors

Pradeep Kumar, Partha Biswas, Biman Bandyopadhyay


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Abstract

Investigations carried out at MP2 and CCSD(T) levels of theory show that water dimers can compete with formic and sulfuric acids in catalyzing the isomerization of methoxy radicals in the lower troposphere. The rate coefficients for water catalyzed reactions showed opposite temperature dependence to that of acid catalyzed reactions and they were found to play an important role in determining the relative impacts of these catalysts under different atmospheric conditions.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
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