![Bis[(1,2,3,4,5-eta)-1-(diphenylphosphino)cyclopentadienyl]iron structure](https://static.chemtradehub.com/structs/121/12150-46-8-ecd2.webp "Bis[(1,2,3,4,5-eta)-1-(diphenylphosphino)cyclopentadienyl]iron structure")
Bis[(1,2,3,4,5-eta)-1-(diphenylphosphino)cyclopentadienyl]iron
CAS Number:
12150-46-8
Molecular Formula:
C34H28FeP2
Dearomative C–C and C–N bond cleavage of 2-arylindoles: transition-metal-free access to 2-aminoarylphenones
Literature Information
Publication Date
2016-01-15
DOI
10.1039/C5QO00394F
Impact Factor
5.281
Authors
Shuang Luo, Ziwei Hu, Qiang Zhu
View Original
Abstract
A transition-metal-free conversion of 2-arylindoles to 2-aminoarylphenones, using environmentally benign O2 as the sole oxidant, has been developed. This novel oxidative dearomatization process involves cleavage of both C–C and C–N bonds followed by new C–C and C–O bond formation. The C2 carbon of an indole scaffold was released in the form of CO2.
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Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
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CAS Number:
19210-12-9
Molecular Formula:
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