Palladium-catalyzed decarboxylative alkoxycarbonylation of potassium aryltrifluoroborates with potassium oxalate monoesters
Literature Information
Publication Date
2015-12-11
DOI
10.1039/C5QO00349K
Impact Factor
5.281
Authors
Jinmin Miao, Ping Fang, Sahota Jagdeep, Haibo Ge
View Original
Abstract
Palladium-catalyzed decarboxylative alkoxycarbonylation of potassium aryltrifluoroborates with potassium oxalate monoesters in the presence of potassium persulfate was performed under mild conditions. A number of benzoyl esters with a wide variety of substituents at different positions were efficiently synthesized with this method. Mechanism of the palladium-catalyzed decarboxylative carbonylation of aryltrifluoroborates was studied, and a radical-mediated Pd(II)/Pd(IV) catalytic cycle was proposed.
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Organic Chemistry Frontiers
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