Synthesis and characterization of quaternary phosphonium-containing, trithiocarbonate RAFT agents
Literature Information
Publication Date
2014-06-27
DOI
10.1039/C4PY00615A
Impact Factor
5.582
Authors
Longhe Zhang, Qiang Tang, R. A. Weiss, Kevin A. Cavicchi
View Original
Abstract
In this article the syntheses of quaternary phosphonium-containing trithiocarbonate RAFT agents (RAFT-PR3, R = Bu and Ph) and their use in the bulk, thermally initiated polymerization of styrene were examined. It was found that the thermal stabilities of RAFT-PR3 were enhanced compared to comparable quaternary ammonium-containing RAFT agents, which significantly improved the retention of the cationic end-functionality of the polystyrene obtained by high temperature bulk polymerization. The crude polystyrene was further purified via column chromatography to yield high purity hemi-telechelic polystyrene cationomers.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
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