Catalyst-free cross-coupling of N-tosylhydrazones with chromium(0) Fischer carbene complexes: a new approach to diarylethanone
Literature Information
Publication Date
2015-08-28
DOI
10.1039/C5QO00241A
Impact Factor
5.281
Authors
Jinghui Yang, Ying Xia, Chen Ma, Haiping Xia, Yan Zhang, Jianbo Wang
View Original
Abstract
Cross-coupling of N-tosylhydrazones with chromium Fischer carbene complexes under catalyst-free conditions has been developed. This protocol employs stable carbene complexes and reactive diazo compounds, which are in situ generated from N-tosylhydrazones. Through hydrolysis of the initially formed methyl enolate products, the diarylethanone derivatives could be obtained in moderate to good yields.
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