Temperature-dependent water solubility of iodine-doped single-walled carbon nanotubes prepared using an electrochemical method

Literature Information

Publication Date 2013-03-08
DOI 10.1039/C3CP50506E
Impact Factor 3.676
Authors

Hayong Song, Yosuke Ishii, Ayar Al-zubaidi, Takenobu Sakai, Shinji Kawasaki


View Original

Abstract

We demonstrate that iodine-doping into single-walled carbon nanotubes (SWCNTs) can be effectively done using an electrochemical method. It is shown by in situ Raman measurements that the iodine-doping level can be easily and finely controlled because de-doping is also possible by changing the polarity. In situ synchrotron XRD measurements reveal that iodine molecules are mainly inserted into the hollow core of SWCNTs. The dispersion state of the iodine-doped SWCNTs in water as a function of temperature is also investigated. It is shown that the iodine-doped SWCNTs can be homogeneously dispersed in water at low temperature (ca. <15 °C).

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