![19-[Chloro(dideuterio)methyl]-19-deuterio-20,20-dideuteriooxyoctatriacontane-18,21-dione structure](https://static.chemtradehub.com/structs/124/1246818-85-8-6244.webp "19-[Chloro(dideuterio)methyl]-19-deuterio-20,20-dideuteriooxyoctatriacontane-18,21-dione structure")
19-[Chloro(dideuterio)methyl]-19-deuterio-20,20-dideuteriooxyoctatriacontane-18,21-dione
CAS Number:
1246818-85-8
Molecular Formula:
C39H75ClO4
Au(i) π-bis(tert-butyldimethylsilyl)acetylene triphenylphosphine complex, an effective pre-catalyst for Au(i)-catalyzed reactions
Literature Information
Publication Date
2015-02-11
DOI
10.1039/C5QO00023H
Impact Factor
5.281
Authors
Dapeng Zhu, Xin Cao, Biao Yu
View Original
Abstract
A linear η2-alkyne π complex of [Ph3PAu]+, namely Au(I) π-bis(tert-butyldimethylsilyl)acetylene triphenylphosphine complex (1), was prepared and characterized. The new complex is found to be shelf-stable and effective for a range of the Au(I)-catalyzed alkyne π activation reactions, including a glycosylation reaction with glycosyl ortho-alkynylbenzoates as donors.
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Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
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