Synthesis and conductivity of hyperbranched poly(triazolium)s with various end-capping groups
Literature Information
Publication Date
2015-11-17
DOI
10.1039/C5PY01735A
Impact Factor
5.582
Authors
Jianhua Wu, Jie Chen, Junfang Wang, Xiaojuan Liao, Meiran Xie, Ruyi Sun
View Original
Abstract
A series of novel hyperbranched poly(triazolium)s with different terminal groups were synthesized by alkylation and anion exchange reactions of the corresponding hyperbranched poly(triazole)s, which were obtained from an AB2-type monomer via Cu(I)-catalyzed azide–alkyne cycloaddition polymerization. The hyperbranched poly(triazolium)s showed high thermal stability with decomposition temperatures of 328–361 °C, and good flexibility, with glass transition temperatures (Tg) ranging from −6.2 to −14.9 °C. Among them, an oligo(ethylene glycol)-terminated hyperbranched poly(triazolium) presented the lowest Tg of −14.9 °C, the highest ionic conductivity (7.70 × 10−6 S cm−1 at 30 °C and 1.02 × 10−3 S cm−1 at 110 °C) and a wide electrochemical stability window of 6.0 V. Therefore, these hyperbranched poly(triazolium)s could act as new electrolyte materials.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
4-(3-((4-Chloro-6-methoxyquinolin-7-yl)oxy)propyl)morpholine
CAS Number:
205448-32-4
Molecular Formula:
C17H21ClN2O3
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