![N-[2,6-Di(9-anthryl)-4-oxido-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl]-1,1,1-trifluoromethanesulfonamide structure](https://static.chemtradehub.com/structs/122/1227374-64-2-cdb5.webp "N-[2,6-Di(9-anthryl)-4-oxido-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl]-1,1,1-trifluoromethanesulfonamide structure")
N-[2,6-Di(9-anthryl)-4-oxido-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl]-1,1,1-trifluoromethanesulfonamide
CAS Number:
1227374-64-2
Molecular Formula:
C49H37F3NO5PS
Chemically crosslinked yet reprocessable epoxidized natural rubber via thermo-activated disulfide rearrangements
Literature Information
Publication Date
2015-04-30
DOI
10.1039/C5PY00459D
Impact Factor
5.582
Authors
L. Imbernon, E. K. Oikonomou, S. Norvez, L. Leibler
View Original
Abstract
The thermo-activated reprocessing ability of a chemically crosslinked epoxidized natural rubber (ENR) is investigated. Disulfide groups are introduced into the rubber using dithiodibutyric acid (DTDB) as a crosslinker. DTDB-cured ENR presents strong elastomeric properties due to the high molecular weight of the rubber and efficient crosslinking. The material behaves like a standard natural rubber until 100 °C and becomes reprocessable above 150 °C, owing to disulfide rearrangements. After grinding to a fine powder, the crosslinked rubber can be reprocessed and recovers most of its initial mechanical properties. The heat-triggered disulfide rearrangements are characterized in terms of stress relaxation, creep/recovery, adhesion tests, and swelling experiments. Comparison is made with ENR samples crosslinked by permanent links.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
4-(4-Chloro-2-methoxyphenyl)-3-fluorobenzoic acid
CAS Number:
1261970-23-3
Molecular Formula:
C14H10ClFO3
4-(3-((4-Chloro-6-methoxyquinolin-7-yl)oxy)propyl)morpholine
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205448-32-4
Molecular Formula:
C17H21ClN2O3
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