Is seven the minimum number of water molecules per ion pair for assured biological activity in ionic liquid–water mixtures?

Literature Information

Publication Date 2015-04-20
DOI 10.1039/C5CP00768B
Impact Factor 3.676
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Abstract

Ionic liquids (ILs) containing small amounts of water are called hydrated ILs and they show diverse physico-chemical properties that are strongly dependent on their water content. Some properties of hydrated ILs, such as biological activity and phase transition behaviour, were found to change non-linearly, with an inflection at a water molecule to ion pair ratio of around 7 : 1. This critical hydration number of ILs has been discussed in this paper with respect to the state of solvated water molecules.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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